An unusual zig-zag 2D copper(i) coordination polymer as an outstanding catalyst for azide–alkyne “click” chemistry at room temperature

A straightforward method for the synthesis of a two-dimensional (2D) new copper(I) coordination polymer, namely Cu(bzpdc), containing the ligand benzophenone 4,4′-dicarboxylate, and its effective use as catalyst for the azide–alkyne click chemistry at room temperature is reported. Zig-zag formation caused by cuprophilic interactions resulted in an unprecedented crystal structure with a very high copper content (45.5% by weight). The catalyst was stable up until 300 °C and tolerant to various solvents, including water. Cu(bzpdc) showed excellent catalytic activity for click reactions of several organic azides and alkynes having different functional groups at room temperature and is comparable to its homogenous analogues. The recyclability of Cu(bzpdc) was also tested and proven to be effective.

Kocaarslan, Azra (author)
Kaya, KeremStockholms universitet,Institutionen för material- och miljökemi (MMK),Istanbul Technical University, Turkey(Swepub:su)Kerem (author)
Atsay, Armagan (author)
Svensson Grape, ErikStockholms universitet,Institutionen för material- och miljökemi (MMK)(Swepub:su)ersv6431 (author)
Chen, JianhongStockholms universitet,Institutionen för material- och miljökemi (MMK)(Swepub:su)jich2514 (author)
Yagci, Yusuf (author)
Stockholms universitetInstitutionen för material- och miljökemi (MMK) (creator_code:org_t)

In:Dalton Transactions: Royal Society of Chemistry (RSC)51:46, s. 17543-175461477-92261477-9234

By the author/editor: Bilgic, Mehmet B ...; Kocaarslan, Azra; Kaya, Kerem; Atsay, Armagan; Svensson Grape, ...; Chen, Jianhong; show more...; Yagci, Yusuf; show less...

About the subject

Kungliga biblioteket hanterar dina personuppgifter i enlighet med EU:s dataskyddsförordning (2018), GDPR. Läs mer om hur det funkar här.
Så här hanterar KB dina uppgifter vid användning av denna tjänst.