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LIBRIS Formathandbok  (Information om MARC21)
FältnamnIndikatorerMetadata
00004648naa a2200613 4500
001oai:gup.ub.gu.se/172008
003SwePub
008240528s2008 | |||||||||||000 ||eng|
024a https://gup.ub.gu.se/publication/1720082 URI
040 a (SwePub)gu
041 a eng
042 9 SwePub
072 7a ref2 swepub-contenttype
072 7a art2 swepub-publicationtype
100a Marks, M. A. W.4 aut
2451 0a Sodic pyroxene and sodic amphibole as potential reference materials for in situ lithium isotope determinations by SIMS
264 1c 2008
520 a Two large pegmatitic crystals of sodic pyroxene (aegirine) and sodic amphibole (arfvedsonite) from the agpaitic igneous Ilimaussaq Complex, south Greenland were found to be suitable as reference materials for in situ Li isotope determinations. Lithium concentrations determined by SIMS and micro-drilled material analysed by MC-ICP-MS generally agreed within analytical uncertainty. The arfvedsonite crystal was homogeneous with [Li] = 639 +/- 51 mu g g(-1) (2s, n = 69, MC-ICP-MS and SIMS results). The aegirine crystal shows strongly developed sector zoning, which is a common feature of aegirines. Using qualitative element mapping techniques (EPMA), the homogeneous core of the crystal was easily distinguished from the outermost sectors of the crystals. The core had a mean [Li] of 47.6 +/- 3.6 mu g g(-1) (2s, n = 33) as determined by SIMS. The seven micro-drilled regions measured by solution MC-ICP-MS returned slightly lower concentrations (41-46 mu g g(-1)), but still overlap with the SIMS data within uncertainty. Based on MC-ICP-MS and SIMS analyses, the variation in delta(7)Li was about 1 parts per thousand in each of the two crystals, which is smaller than that in widely used glass reference materials, making these two samples suitable to serve as reference materials. There was, however, a significant offset between the results of MC-ICP-MS and SIMS. The latter deviated from the MC-ICP-MS results by -6.0 +/- 1.9 parts per thousand (2s) for the amphibole and by -3.9 +/- 1.9 parts per thousand (2s) for the aegirine. This indicates the presence of a significant matrix effect in SIMS determinations of Li isotopes for amphibole and pyroxene relative to the basalt glasses used for calibration. Based on the MC-ICP-MS results, mean delta(7)Li values of +0.7 +/- 1.2 parts per thousand (2s, n = 10) for the arfvedsonite crystal and of -3.7 +/- 1.2 parts per thousand (2s, n = 7) for the core of the aegirine crystal were calculated. Adopting these values, SIMS users can correct for the specific IMF (instrumental mass fractionation) of the ion probe used. We propose that these two crystals serve as reference materials for in situ Li isotope determinations by SIMS and pieces of these two crystals are available from the first author upon request.
650 7a NATURVETENSKAPx Geovetenskap och miljövetenskapx Geokemi0 (SwePub)105062 hsv//swe
650 7a NATURAL SCIENCESx Earth and Related Environmental Sciencesx Geochemistry0 (SwePub)105062 hsv//eng
650 7a NATURVETENSKAPx Geovetenskap och miljövetenskap0 (SwePub)1052 hsv//swe
650 7a NATURAL SCIENCESx Earth and Related Environmental Sciences0 (SwePub)1052 hsv//eng
650 7a NATURVETENSKAPx Geovetenskap och miljövetenskapx Geologi0 (SwePub)105042 hsv//swe
650 7a NATURAL SCIENCESx Earth and Related Environmental Sciencesx Geology0 (SwePub)105042 hsv//eng
653 a reference material
653 a li isotopes
653 a aegirine
653 a arfvedsonite
653 a ilimaussaq
653 a south greenland
653 a li isotope
653 a ilimaussaq intrusion
653 a peridotite xenoliths
653 a silicate-glasses
653 a high-temperature
653 a icp-ms
653 a fractionation
653 a boron
653 a mantle
700a Rudnick, R. L.4 aut
700a Ludwig, T.4 aut
700a Marschall, H.4 aut
700a Zack, Thomas,d 1968u Gothenburg University,Göteborgs universitet,Institutionen för geovetenskaper,Department of Earth Sciences4 aut0 (Swepub:gu)xzackt
700a Halama, R.4 aut
700a McDonough, W. F.4 aut
700a Rost, D.4 aut
700a Wenzel, T.4 aut
700a Vicenzi, E. P.4 aut
700a Savov, I. P.4 aut
700a Altherr, R.4 aut
700a Markl, G.4 aut
710a Göteborgs universitetb Institutionen för geovetenskaper4 org
773t Geostandards and Geoanalytical Researchg 32:3, s. 295-310q 32:3<295-310x 1639-4488
8564 8u https://gup.ub.gu.se/publication/172008

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