Near-Infrared Luminescence from Visible-Light-Sensitized Ruthenium(II)-Neodymium(III) Heterobimetallic Bridged Complexes Containing Alkoxy(silyl) Functional Groups

↓ Direkt till sidans innehåll
↓ Direkt till sidans sekundära innehåll (sidomenyn)

Sökning: WFRF:(Sabio J. M.) > Near-Infrared Lumin...

LIBRIS Formathandbok (Information om MARC21)

Fältnamn	Indikatorer	Metadata
000		04401naa a2200577 4500
001		oai:research.chalmers.se:fd5b7463-37d2-42f9-b158-33b98b3d535a
003		SwePub
008		200430s2020 \| \|\|\|\|\|\|\|\|\|\|\|000 \|\|eng\|
024	7	a https://research.chalmers.se/publication/5161602 URI
024	7	a https://doi.org/10.21577/0103-5053.201902332 DOI
024	7	a https://research.chalmers.se/publication/5166942 URI
024	7	a https://research.chalmers.se/publication/5161672 URI
040		a (SwePub)cth
041		a engb eng
042		9 SwePub
072	7	a art2 swepub-publicationtype
072	7	a ref2 swepub-contenttype
100	1	a Sábio, Rafael M.u Universidade Estadual Paulista (UNESP),São Paulo State University (UNESP)4 aut
245	1 0	a Near-Infrared Luminescence from Visible-Light-Sensitized Ruthenium(II)-Neodymium(III) Heterobimetallic Bridged Complexes Containing Alkoxy(silyl) Functional Groups
264		c 2020
264	1	b Sociedade Brasileira de Quimica (SBQ),c 2020
338		a electronic2 rdacarrier
520		a New infrared emitting d-f (ruthenium(II)–neodymium(III)) heterobimetallic complexes with alkoxy(silyl) functional groups have been prepared. Visible excitation evidenced energy transfer processes from the ruthenium(II) donor to neodymium(III) acceptors leading to infrared emission. Energy transfer rates (kEnT) and efficiency of energy transfer (ηEnT) are, respectively, 0.61 × 107 s-1 and 44% for RuL1–NdL3 complex. Larger values of kEnT (3.04 × 107 s-1) and ηEnT (84%) were detected for RuL2–NdL4 complex. RuL1–NdL3 and RuL2–NdL4 complexes were fully characterized by elementary analysis (EA), mass spectrometry (MS), Fourier transform infrared spectroscopy (FTIR) and Fourier transform Raman spectroscopy (FT-Raman). Total correlation spectroscopy (TOCSY1D), 1H{13C} heteronuclear single quantum correlation (HSQC) and 1H{13C} heteronuclear multiple bond correlation (HMBC) nuclear magnetic resonance (NMR) analyses were also carried out to characterize NdL3 and RuL1–NdL3 complexes. The presence of trialkoxysilyl-substituted ligands would allow further grafting onto any silica or silicated surface aiming at applications as new luminescent near infrared (NIR)-emitting biosensors or biomarkers.
650	7	a NATURVETENSKAPx Fysikx Atom- och molekylfysik och optik0 (SwePub)103022 hsv//swe
650	7	a NATURAL SCIENCESx Physical Sciencesx Atom and Molecular Physics and Optics0 (SwePub)103022 hsv//eng
650	7	a NATURVETENSKAPx Fysikx Annan fysik0 (SwePub)103992 hsv//swe
650	7	a NATURAL SCIENCESx Physical Sciencesx Other Physics Topics0 (SwePub)103992 hsv//eng
650	7	a NATURVETENSKAPx Kemix Organisk kemi0 (SwePub)104052 hsv//swe
650	7	a NATURAL SCIENCESx Chemical Sciencesx Organic Chemistry0 (SwePub)104052 hsv//eng
653		a D-f energy transfer
653		a Neodymium(III)
653		a Ruthenium(II)
653		a Grafting trialkoxysilyl group
653		a NIR luminescent complexes
653		a Silylated heterobimetallic complexes
653		a Visible
700	1	a Santagneli, Silvia H.u Universidade Estadual Paulista (UNESP),São Paulo State University (UNESP)4 aut
700	1	a Gressier, Marie4 aut
700	1	a Caiut, José M.A.u Universidade de Sao Paulo (USP),University of Sao Paulo (USP)4 aut
700	1	a Pazin, Wallance M.u Universidade de Sao Paulo (USP),University of Sao Paulo (USP)4 aut
700	1	a Rosa Da Silva, Robson,d 1988u Chalmers tekniska högskola,Chalmers University of Technology4 aut0 (Swepub:cth)rosa
700	1	a Ribeiro, Sidney J.L.u Universidade Estadual Paulista (UNESP),São Paulo State University (UNESP)4 aut
700	1	a Menu, Marie Joëlle4 aut
710	2	a Universidade Estadual Paulista (UNESP)b Universidade de Sao Paulo (USP)4 org
773	0	t Journal of the Brazilian Chemical Societyd : Sociedade Brasileira de Quimica (SBQ)g 31:4, s. 694-702q 31:4<694-702x 0103-5053x 1678-4790
856	4	u https://research.chalmers.se/publication/516694/file/516694_Fulltext.pdfx primaryx freey FULLTEXT
856	4	u https://doi.org/10.21577/0103-5053.20190233
856	4 8	u https://research.chalmers.se/publication/516160
856	4 8	u https://doi.org/10.21577/0103-5053.20190233
856	4 8	u https://research.chalmers.se/publication/516694
856	4 8	u https://research.chalmers.se/publication/516167

Hitta via bibliotek

Journal of the Brazilian Chemical Society (Sök värdpublikationen i LIBRIS)

Till lärosätets databas

Hitta mer i SwePub

Av författaren/redakt...: Sábio, Rafael M.; Santagneli, Silv ...; Gressier, Marie; Caiut, José M.A.; Pazin, Wallance ...; Rosa Da Silva, R ...; visa fler...; Ribeiro, Sidney ...; Menu, Marie Joël ...; visa färre...

Om ämnet

NATURVETENSKAP: NATURVETENSKAP; och Fysik; och Atom och molekyl ...

NATURVETENSKAP: NATURVETENSKAP; och Fysik; och Annan fysik

NATURVETENSKAP: NATURVETENSKAP; och Kemi; och Organisk kemi

Artiklar i publikationen: Journal of the B ...

Av lärosätet: Chalmers tekniska högskola

Sök utanför SwePub

Sök vidare i:: Google; Google Book Search; Google Scholar

Kungliga biblioteket hanterar dina personuppgifter i enlighet med EU:s dataskyddsförordning (2018), GDPR. Läs mer om hur det funkar här.
Så här hanterar KB dina uppgifter vid användning av denna tjänst.

LIBRIS.kb.se