Search: WFRF:(Yan Max)
> (2020-2024) >
Hemicellulose conte...
Hemicellulose content affects the properties of cellulose nanofibrils produced from softwood pulp fibres by LPMO
-
- Koskela, Salla (author)
- KTH,Glykovetenskap,Albanova VinnExcellence Center for Protein Technology, ProNova,Wallenberg Wood Science Center,Fiber- och polymerteknologi,Division of Glycoscience, Department of Chemistry, KTH Royal Institute of Technology, AlbaNova University Centre, SE-106 91 Stockholm, Sweden;Wallenberg Wood Science Center, Department of Fiber and Polymer Technology, KTH Royal Institute of Technology, SE-100 44 Stockholm, Sweden
-
- Zha, Li (author)
- KTH,Glykovetenskap,Albanova VinnExcellence Center for Protein Technology, ProNova,Division of Glycoscience, Department of Chemistry, KTH Royal Institute of Technology, AlbaNova University Centre, SE-106 91 Stockholm, Sweden
-
- Wang, Shennan, Dr. 1992- (author)
- KTH,Glykovetenskap,Albanova VinnExcellence Center for Protein Technology, ProNova,Division of Glycoscience, Department of Chemistry, KTH Royal Institute of Technology, AlbaNova University Centre, SE-106 91 Stockholm, Sweden
-
show more...
-
- Yan, Max (author)
- KTH,Fotonik,Department of Applied Physics, KTH Royal Institute of Technology, SE-114 19 Stockholm, Sweden
-
- Zhou, Qi (author)
- KTH,Albanova VinnExcellence Center for Protein Technology, ProNova,Glykovetenskap,Wallenberg Wood Science Center,Fiber- och polymerteknologi,Division of Glycoscience, Department of Chemistry, KTH Royal Institute of Technology, AlbaNova University Centre, SE-106 91 Stockholm, Sweden;Wallenberg Wood Science Center, Department of Fiber and Polymer Technology, KTH Royal Institute of Technology, SE-100 44 Stockholm, Sweden
-
show less...
-
(creator_code:org_t)
- 2022
- 2022
- English.
-
In: Green Chemistry. - : Royal Society of Chemistry (RSC). - 1463-9262 .- 1463-9270.
- Related links:
-
https://doi.org/10.1...
-
show more...
-
https://urn.kb.se/re...
-
https://doi.org/10.1...
-
https://urn.kb.se/re...
-
show less...
Abstract
Subject headings
Close
- Lytic polysaccharide monooxygenase (LPMO)-catalysed oxidation of cellulose has emerged as a green alternative to chemical modifications in the production of cellulose nanofibrils (CNFs) from wood pulp fibres. The effect of the hemicellulose content of the starting pulp fibres on the oxidation capabilities of cellulose-active LPMO is important and has not been investigated previously. In this study, the production of LPMO-oxidised CNFs was evaluated on two commercial softwood pulp fibres with different hemicellulose contents. Thin and colloidally stable CNFs were readily obtained from kraft pulp with a hemicellulose content of 16%. The preserved hemicellulose fraction in the kraft pulp enhanced the access of LPMO into the fibre cell wall, enabling the production of homogeneous CNFs with a thin width of 3.7 ± 1.7 nm. By contrast, the LPMO-oxidised dissolving pulp with a lower hemicellulose content of 4% could only be partially disintegrated into thin CNFs, leaving a large amount of cellulose microfibril aggregates with widths of around 50 to 100 nm. CNFs disintegrated from the LPMO-oxidised kraft pulp could be processed into nanopapers with excellent properties including an optical transmittance of 86%, tensile strength of 260 MPa, and Young's modulus of 16.9 GPa. Such CNFs also showed acid-triggered nanofibril gelation owing to the introduced carboxyl groups on cellulose microfibril surfaces. These results indicate that the inherent hemicelluloses present in the wood cell wall are essential for LPMO-mediated CNF production from wood pulp fibres.
Subject headings
- TEKNIK OCH TEKNOLOGIER -- Materialteknik (hsv//swe)
- ENGINEERING AND TECHNOLOGY -- Materials Engineering (hsv//eng)
- TEKNIK OCH TEKNOLOGIER -- Industriell bioteknik -- Annan industriell bioteknik (hsv//swe)
- ENGINEERING AND TECHNOLOGY -- Industrial Biotechnology -- Other Industrial Biotechnology (hsv//eng)
- TEKNIK OCH TEKNOLOGIER -- Materialteknik -- Pappers-, massa- och fiberteknik (hsv//swe)
- ENGINEERING AND TECHNOLOGY -- Materials Engineering -- Paper, Pulp and Fiber Technology (hsv//eng)
Keyword
- LPMO nanofibril nanocellulose cellulose pulp fibre CNF
- Biotechnology
- Bioteknologi
- Materials Science and Engineering
- Teknisk materialvetenskap
Publication and Content Type
- ref (subject category)
- art (subject category)
Find in a library
To the university's database