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Unraveling Enyne Bo...
Unraveling Enyne Bonding via Dehydrogenation-Hydrogenation Processes in On-Surface Synthesis with Terminal Alkynes
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- Lyu, Yuanhao (author)
- Chinese Acad Sci, Peoples R China; Univ Chinese Acad Sci, Peoples R China
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- Gao, Feng (author)
- Chinese Acad Sci, Peoples R China; Univ Chinese Acad Sci, Peoples R China
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- Cheng, Peng (author)
- Chinese Acad Sci, Peoples R China; Univ Chinese Acad Sci, Peoples R China
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- Chen, Lan (author)
- Chinese Acad Sci, Peoples R China; Univ Chinese Acad Sci, Peoples R China; Songshan Lake Mat Lab, Peoples R China
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- Klyatskaya, Svetlana (author)
- Karlsruhe Inst Technol KIT, Germany
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- Ruben, Mario (author)
- Karlsruhe Inst Technol KIT, Germany; Univ Strasbourg, France
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- Rosén, Johanna (author)
- Linköpings universitet,Materialdesign,Tekniska fakulteten
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- Barth, Johannes V. (author)
- Tech Univ Munich, Germany
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- Björk, Jonas (author)
- Linköpings universitet,Materialdesign,Tekniska fakulteten
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- Wu, Kehui (author)
- Chinese Acad Sci, Peoples R China; Univ Chinese Acad Sci, Peoples R China; Songshan Lake Mat Lab, Peoples R China
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- Zhang, Yi-Qi (author)
- Chinese Acad Sci, Peoples R China
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(creator_code:org_t)
- 2024
- 2024
- English.
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In: Advanced Materials Interfaces. - : WILEY. - 2196-7350.
- Related links:
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
Subject headings
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- On-surface reactions of terminal alkynes in ultrahigh vacuum have attracted widespread attention due to their high technological promise. However, employing different precursors and substrate materials often intricate reaction schemes appear far from being well-understood. Thus, recent investigations of alkyne coupling on noble metal surfaces suggest non-dehydrogenative scenarios, contradicting earlier reports. Herein, the study employs noncontact atomic force microscopy (nc-AFM) with high spatial resolution to conclusively characterize exemplary alkyne coupling products. Contrary to initial interpretations proposing dehydrogenative homocoupling on Ag(111), bond-resolved AFM imaging reveals the expression of enyne motifs. Based on complementary, extensive density functional theory calculations, the pertaining reaction mechanisms are explored. It is proposed that enyne formation initiates with a direct carbon-carbon coupling between two alkyne groups, followed by surface-assisted dehydrogenation-hydrogenation processes. Thereby consecutive steps of atomic hydrogen cleavage, surface migration and recombination to a different carbon atom enable bridging via carbon-carbon double bonding. The new results shed light on subtle, but crucial surface-mediated hydrogen transfer processes involved in the chemical bond formation, which are suggested to be of general relevance in on-surface synthesis. Terminal alkyne coupling on Ag(111) in ultrahigh vacuum is conclusively examined by bond-resolved atomic force microscopy and density functional theory modeling. The prevailing bonding motif is the enyne moiety, originating from a distinct surface-mediated dehydrogenation-hydrogenation reaction pathway. The findings highlight the important role of hydrogen transfer in the course of on-surface synthesis procedures. image
Subject headings
- NATURVETENSKAP -- Fysik -- Den kondenserade materiens fysik (hsv//swe)
- NATURAL SCIENCES -- Physical Sciences -- Condensed Matter Physics (hsv//eng)
Keyword
- density functional theory; graphdiyne; non-contact atomic force microscopy; on-surface synthesis; terminal alkyne
Publication and Content Type
- ref (subject category)
- art (subject category)
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- By the author/editor
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Lyu, Yuanhao
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Gao, Feng
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Cheng, Peng
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Chen, Lan
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Klyatskaya, Svet ...
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Ruben, Mario
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show more...
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Rosén, Johanna
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Barth, Johannes ...
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Björk, Jonas
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Wu, Kehui
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Zhang, Yi-Qi
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- About the subject
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- NATURAL SCIENCES
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NATURAL SCIENCES
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and Physical Science ...
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and Condensed Matter ...
- Articles in the publication
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Advanced Materia ...
- By the university
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Linköping University