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Sökning: onr:"swepub:oai:DiVA.org:umu-2699" > Absorption spectrom...

LIBRIS Formathandbok  (Information om MARC21)
FältnamnIndikatorerMetadata
00002894naa a2200325 4500
001oai:DiVA.org:umu-2699
003SwePub
008071101s2006 | |||||||||||000 ||eng|
024a https://urn.kb.se/resolve?urn=urn:nbn:se:umu:diva-26992 URI
024a https://doi.org/10.1366/0003702067789990492 DOI
040 a (SwePub)umu
041 a engb eng
042 9 SwePub
072 7a ref2 swepub-contenttype
072 7a art2 swepub-publicationtype
100a Axner, Oveu Umeå universitet,Institutionen för fysik4 aut0 (Swepub:umu)ovax0001
2451 0a Absorption spectrometry by narrowband light in optically saturated and optically pumped collision and doppler broadened gaseous media under arbitrary optical thickness conditions
264 c 2016-08-30
264 1a New York :b Society for applied spectroscopy,c 2006
338 a print2 rdacarrier
520 a This work examines absorption spectrometry by narrowband light in gaseous media with arbitrary optical thickness when the light induces optical saturation or optical pumping. Two quantities are defined: the observed absorbance, Aobs, and the true absorbance, Atrue. The former is the absorbance that is measured under the existing conditions, whereas the latter represents the absorbance one would measure if the light acted solely as a probe of the populations of the various levels, and it is therefore directly proportional to the concentration or density of absorbers. A general integral equation for the propagation of light in media of arbitrary optical thickness in which the light influences the populations of the levels involved is derived. This expression is transcendental in the observed absorbance and cannot be solved analytically. It is shown that an analytical expression can be derived by investigating the inverse relationship, i.e., Atrue = f(Aobs). Inasmuch as collision and Doppler broadened media react differently to optical saturation, they are considered separately. It is shown that a nonlinear response results if the medium is optically saturated (or pumped) and not optically thin. Expressions for the error introduced if the technique of standard additions is uncritically applied to such a system are derived.
700a Schmidt, Florian M.u Umeå universitet,Institutionen för fysik4 aut0 (Swepub:umu)flnsct02
700a Foltynowicz, Aleksandrau Umeå universitet,Institutionen för fysik4 aut0 (Swepub:umu)alafoz03
700a Gustafsson, Jörgen4 aut
700a Omenetto, Nicoló4 aut
700a Winefordner, James D.4 aut
710a Umeå universitetb Institutionen för fysik4 org
773t Applied Spectroscopyd New York : Society for applied spectroscopyg 60:11, s. 1217-1240q 60:11<1217-1240x 0003-7028x 1943-3530
8564 8u https://urn.kb.se/resolve?urn=urn:nbn:se:umu:diva-2699
8564 8u https://doi.org/10.1366/000370206778999049

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