SwePub
Sök i LIBRIS databas

  Extended search

WFRF:(Syrén Per Olof)
 

Search: WFRF:(Syrén Per Olof) > Biocatalysis for te...

Biocatalysis for terpene-based polymers

Farhat, Wissam (author)
KTH,Ytbehandlingsteknik,Science for Life Laboratory, SciLifeLab
Stamm, Arne (author)
KTH,Science for Life Laboratory, SciLifeLab,Ytbehandlingsteknik
Robert-Monpate, Maxime (author)
KTH,Ytbehandlingsteknik,Science for Life Laboratory, SciLifeLab,Ecole Super Chim Organ & Minerale, 1 Allee Reseau Jean Marie Buckmaster, F-60200 Compiegne, France
show more...
Biundo, Antonino (author)
KTH,Science for Life Laboratory, SciLifeLab,Ytbehandlingsteknik
Syrén, Per-Olof (author)
KTH,Science for Life Laboratory, SciLifeLab,Ytbehandlingsteknik
show less...
 (creator_code:org_t)
2019-02-21
2019
English.
In: Zeitschrift für Naturforschung C - A Journal of Biosciences. - : WALTER DE GRUYTER GMBH. - 0939-5075 .- 1865-7125. ; 74:3-4, s. 90-99
  • Journal article (peer-reviewed)
Abstract Subject headings
Close  
  • Accelerated generation of bio-based materials is vital to replace current synthetic polymers obtained from petroleum with more sustainable options. However, many building blocks available from renewable resources mainly contain unreactive carbon-carbon bonds, which obstructs their efficient polymerization. Herein, we highlight the potential of applying biocatalysis to afford tailored functionalization of the inert carbocyclic core of multicyclic terpenes toward advanced materials. As a showcase, we unlock the inherent monomer reactivity of norcamphor, a bicyclic ketone used as a monoterpene model system in this study, to afford polyesters with unprecedented backbones. The efficiencies of the chemical and enzymatic Baeyer-Villiger transformation in generating key lactone intermediates are compared. The concepts discussed herein are widely applicable for the valorization of terpenes and other cyclic building blocks using chemoenzymatic strategies.

Subject headings

NATURVETENSKAP  -- Kemi -- Polymerkemi (hsv//swe)
NATURAL SCIENCES  -- Chemical Sciences -- Polymer Chemistry (hsv//eng)

Keyword

biocatalysis
biopolymers
oxidoreductases
polyesters
terpenes

Publication and Content Type

ref (subject category)
art (subject category)

Find in a library

To the university's database

Search outside SwePub

Kungliga biblioteket hanterar dina personuppgifter i enlighet med EU:s dataskyddsförordning (2018), GDPR. Läs mer om hur det funkar här.
Så här hanterar KB dina uppgifter vid användning av denna tjänst.

 
pil uppåt Close

Copy and save the link in order to return to this view