Solvent Exchange and Complex Formation Reactions of Pd(II) in Aqueous Solution. Mechanistic Information from High Pressure Studies

• High pressure NMR and stopped-flow techniques have been employed to study a series of water exchange and complex formation reactions of Pd(II) outlined in (1) and (2). The volumes of activation show an interesting correlation with the partial molar volume of the entering ligand and underline the operation of an associative substitution mechanism in all cases.

• High pressure NMR and stopped-flow techniques have been employed to study a series of water exchange and complex formation reactions of Pd(II) outlined in (1) and (2). The volumes of activation show an interesting correlation with the partial molar volume of the entering ligand and underline the operation of an associative substitution mechanism in all cases.

Subject headings

NATURVETENSKAP  -- Kemi -- Oorganisk kemi (hsv//swe)

NATURAL SCIENCES  -- Chemical Sciences -- Inorganic Chemistry (hsv//eng)

NATURVETENSKAP  -- Kemi -- Fysikalisk kemi (hsv//swe)

NATURAL SCIENCES  -- Chemical Sciences -- Physical Chemistry (hsv//eng)

Keyword

Solvent exchange

Complex formatioon

Palladium(II)

Volume of activation

Associative reactions

High pressure stopped-flow

High pressure NMR

High Pressure NMR

High pressure stopped-Flow

Activation volume

Reaction mechanism

Associative mechanism

Publication and Content Type

art (subject category)

ref (subject category)