Serendipitous and Targeted Synthesis of High Nuclearity Clusters: Carbonate and Oxalate Encapsulating Silver Alkynides

Serendipitous and Targeted Synthesis of High Nuclearity Clusters : Carbonate and Oxalate Encapsulating Silver Alkynides

Silver coordination compounds of the [Ag3L2] (where L = Bu-t-C=C) family having perchlorate counterions exhibit template-driven self-assembly of the common square pyramidal building block. This behavior is similar to previously described observations; however, important differences arise from counterion-silver interactions. Penta- and hexameric clusters encapsulating chloride and oxalate, respectively, were crystallographically characterized. A high nuclearity cluster [(CO3)(3)(H2O)subset of Ag38L20](12+) was formed upon extended exposure to an ambient atmosphere by trapping three carbonates and one water molecule.

Orthaber, Andreas,1979-Uppsala universitet,Syntetisk molekylär kemi(Swepub:uu)ortan368 (författare)
Uppsala universitetSyntetisk molekylär kemi (creator_code:org_t)

Ingår i:Crystal Growth & Design: American Chemical Society (ACS)20:7, s. 4232-42371528-74831528-7505

Om ämnet

Kungliga biblioteket hanterar dina personuppgifter i enlighet med EU:s dataskyddsförordning (2018), GDPR. Läs mer om hur det funkar här.
Så här hanterar KB dina uppgifter vid användning av denna tjänst.