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Solvent and Counter...
Solvent and Counter-Ion Induced Coordination Environment Changes Towards Ag-I Coordination Polymers
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- Gupta, Arvind Kumar (författare)
- Uppsala universitet,Syntetisk molekylär kemi
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- Morales Salazar, Daniel (författare)
- Uppsala universitet,Syntetisk molekylär kemi
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- Orthaber, Andreas, 1979- (författare)
- Uppsala universitet,Syntetisk molekylär kemi
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(creator_code:org_t)
- 2019-08-05
- 2019
- Engelska.
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Ingår i: European Journal of Inorganic Chemistry. - : WILEY-V C H VERLAG GMBH. - 1434-1948 .- 1099-1948 .- 1099-0682. ; 2019:33, s. 3740-3744
- Relaterad länk:
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https://urn.kb.se/re...
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visa fler...
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https://doi.org/10.1...
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Abstract
Ämnesord
Stäng
- A series of silver coordination polymers based on the 9,9 '-bis(4,5-diazafluorene) (BDF-H-2) ligand is presented. The choice of counterions and reaction conditions dictate the observed topology on the final systems by influencing the silver coordination environment. Coordination modes, flexibility of the ligand and extended pi-pi stacking interactions have allowed the preparation and crystallographic characterisation of one 1D- and three 2D-coordination polymers: 1D-[Ag(BDF-H-2)(DMSO)](n)(X)(n) (where X = OTf- and ClO4-); 1D-[Ag-2(BDF-H-2) m(1)-(TfO)(2),m(2)-(TfO)(2)](n)(TfO)(n), and 2D-[Ag-2(BDF-H-2)(3)](n)(PF6)(2n).
Ämnesord
- NATURVETENSKAP -- Kemi -- Oorganisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Inorganic Chemistry (hsv//eng)
Nyckelord
- Coordination polymers
- Diazafluorenes
- Solvent effects
- Silver
- Topology
- polymers
Publikations- och innehållstyp
- ref (ämneskategori)
- art (ämneskategori)
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