Synthesis and characterization of Co(II) and Ni(II) complexes of 2,5-diphenyl-3,4-bis(2-pyridyl)-cyclopentadienone (L). X-ray crystal structures of CoLCl2.0.5CH3CN and NiLBr2.CHCl3

The preparation and properties of [M(chelate)X2] complexes are reported, where M = Co(II) or Ni(II), chelate = 2,5-diphenyl-3,4-bis(2-pyridyl)cyclopentadienone and X = Cl or Br. These complexes have been characterized by elemental analyses and spectroscopic methods. The crystal and molecular structures of CoLCl2·0.5CH3CN (1) and NiLBr2·CHCl3 (4) have been determined by X-ray crystallography. Compound (1) crystallizes in the triclinic space group P-1, different from that of CoLCl2 (monoclinic space group P21/c) that we have reported previously. Compound (4) crystallizes in the monoclinic space group P21/n. Both CoLCl2 and NiLBr2 complexes are pseudo-tetrahedral, and utilization is made of the electronic and vibrational spectra in the structural diagnosis of CoLBr2 and NiLCl2.

Langer, Vratislav,1949Chalmers tekniska högskola,Chalmers University of Technology(Swepub:cth)langer (författare)
Amiri, AhmadIsfahan University of Technology (författare)
Mallakpour, ShadpourIsfahan University of Technology (författare)
Afshar, FarzanehIsfahan University of Technology (författare)
Isfahan University of TechnologyChalmers tekniska högskola (creator_code:org_t)

Av författaren/redakt...: Amirnasr, Mehdi; Langer, Vratisla ...; Amiri, Ahmad; Mallakpour, Shad ...; Afshar, Farzaneh

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