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In situ determination of N-2 broadening coefficients in flames for rotational CARS thermometry

Gao, Yi (author)
Bohlin, Alexis (author)
Lund University,Lunds universitet,Förbränningsfysik,Fysiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Combustion Physics,Department of Physics,Departments at LTH,Faculty of Engineering, LTH
Seeger, Thomas (author)
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Bengtsson, Per-Erik (author)
Lund University,Lunds universitet,Förbränningsfysik,Fysiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Combustion Physics,Department of Physics,Departments at LTH,Faculty of Engineering, LTH
Kliewer, Christopher J. (author)
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 (creator_code:org_t)
Elsevier BV, 2013
2013
English.
In: Proceedings of the Combustion Institute. - : Elsevier BV. - 1540-7489. ; 34, s. 3637-3644
  • Journal article (peer-reviewed)
Abstract Subject headings
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  • Total N-2 S-branch broadening coefficients have been measured in situ as a function of radial position in a highly sooting ethylene diffusion flame by the use of time-resolved dual-broadband picosecond pure rotational CARS (RCARS). Time-domain measurements of the J-dependent N-2 rotational coherence decays in the flame were used to determine the broadening coefficients, and these coefficients were then used in the spectral fitting routine for the determination of temperature and [O-2]/[N-2] ratio in the flame. Corrections of up to 125 K are found when compared to spectral fitting using an ECS self-broadened N-2 linewidth model. The presented technique effectively takes into account contributions to the N-2 linewidths from all collision partners without any a priori knowledge of relative species concentrations. Published by Elsevier Inc. on behalf of The Combustion Institute.

Subject headings

NATURVETENSKAP  -- Fysik -- Atom- och molekylfysik och optik (hsv//swe)
NATURAL SCIENCES  -- Physical Sciences -- Atom and Molecular Physics and Optics (hsv//eng)

Keyword

Time-resolved spectroscopy
Raman linewidths
CARS
Ultrafast
Soot

Publication and Content Type

art (subject category)
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