Sökning: L773:0108 7681 > Li3+δVC6O13: a shor...
Fältnamn | Indikatorer | Metadata |
---|---|---|
000 | 02537naa a2200385 4500 | |
001 | oai:DiVA.org:uu-67732 | |
003 | SwePub | |
008 | 060928s2004 | |||||||||||000 ||eng| | |
024 | 7 | a https://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-677322 URI |
024 | 7 | a https://doi.org/10.1107/S01087681040130962 DOI |
040 | a (SwePub)uu | |
041 | a engb eng | |
042 | 9 SwePub | |
072 | 7 | a ref2 swepub-contenttype |
072 | 7 | a art2 swepub-publicationtype |
100 | 1 | a Höwing, Jonasu Uppsala universitet,Institutionen för materialkemi,Strukturkemi,strukturkemi4 aut |
245 | 1 0 | a Li3+δVC6O13: a short-range-ordered lithium insertion mechanism |
264 | 1 | c 2004 |
338 | a print2 rdacarrier | |
520 | a The structures of Li3 V6O13 and Li3+V6O13, 0.3, have been determined by single-crystal X-ray diffraction. Both compounds have the space group C2/m, with very similar cell parameters. In Li3V6O13, the Li atoms are found in the Wyckoff positions 4(i) and 2(b) with multiplicities of four and two, respectively. Since Li3V6O13 exhibits no superstructure reflections, it is concluded that Li3V6O13 contains one disordered lithium ion in an otherwise ordered centrosymmetric structure. On inserting more lithium into the structure, the Li3+V6O13 phase is formed with the homogeneity range 0 < < 1. It is concluded that the site for the extra inserted lithium ion is closely coupled to the position of the disordered lithium ion in Li3V6O13. A mechanism for this behaviour and for the further formation of the Li6V6O13 end-phase in the LixV6O13 system is proposed. | |
650 | 7 | a NATURVETENSKAPx Kemix Oorganisk kemi0 (SwePub)104042 hsv//swe |
650 | 7 | a NATURAL SCIENCESx Chemical Sciencesx Inorganic Chemistry0 (SwePub)104042 hsv//eng |
653 | a lithium-ion battery | |
653 | a vanadium oxide | |
653 | a insertion mechanism | |
653 | a disorder | |
653 | a Inorganic chemistry | |
653 | a Oorganisk kemi | |
700 | 1 | a Gustafsson, Torbjörnu Uppsala universitet,Institutionen för materialkemi,Strukturkemi,strukturkemi4 aut0 (Swepub:uu)tgu19364 |
700 | 1 | a Thomas, Johnu Uppsala universitet,Institutionen för materialkemi,Strukturkemi,strukturkemi4 aut0 (Swepub:uu)joshthom |
710 | 2 | a Uppsala universitetb Institutionen för materialkemi4 org |
773 | 0 | t Acta Crystallographicag B60, s. 382-387q B60<382-387x 0108-7681 |
856 | 4 | u http://journals.iucr.org/ |
856 | 4 8 | u https://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-67732 |
856 | 4 8 | u https://doi.org/10.1107/S0108768104013096 |
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