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catena-Poly[[chloro...
catena-Poly[[chloro(pyridinium-3-carboxylato-κO)zinc(II)]-μ-nicotinato-κ2O:N]
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- Ghazzali, Mohamed I D M, 1974 (författare)
- Chalmers tekniska högskola,Chalmers University of Technology
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Abu-Youssef, Morsy A.M. (författare)
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- Langer, Vratislav, 1949 (författare)
- Chalmers tekniska högskola,Chalmers University of Technology
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(creator_code:org_t)
- 2007
- 2007
- Engelska.
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Ingår i: Acta Crystallographica Section E: Structure Reports Online. - 1600-5368. ; E63:1, s. m114-m116
- Relaterad länk:
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https://research.cha...
Abstract
Ämnesord
Stäng
- The title bis-nicotinate zinc chloride, [Zn(C6H4NO2)Cl(C6H5NO2)]n, has an infinite head-to-tail one-dimensional chain structure. The compound was synthesized under mild hydrothermal conditions. The ZnII atom exhibits a distorted tetrahedral coordination geometry. The structure is statistically disordered, with 0.5 site occupancy for the Zn atom and the H atom located on the pyridine N atom. As a result, Zn positions in the crystal structure alternate between two sites related by a crystallographic twofold axis and rows of molecules are formed, supported by strong N-H...O hydrogen bonds.
Ämnesord
- NATURVETENSKAP -- Kemi -- Fysikalisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Physical Chemistry (hsv//eng)
Nyckelord
- X-ray crystal structure
- 1D chain
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