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LIBRIS Formathandbok  (Information om MARC21)
FältnamnIndikatorerMetadata
00003003naa a2200349 4500
001oai:DiVA.org:kth-166861
003SwePub
008150520s2015 | |||||||||||000 ||eng|
024a https://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-1668612 URI
024a https://doi.org/10.1002/adfm.2015016432 DOI
040 a (SwePub)kth
041 a engb eng
042 9 SwePub
072 7a ref2 swepub-contenttype
072 7a art2 swepub-publicationtype
100a Mongkhontreerat, Surinthrau KTH,Ytbehandlingsteknik4 aut0 (Swepub:kth)u1khfnor
2451 0a Beyond state of the art honeycomb membranes :b High performance ordered arrays from multi-programmable linear-dendritic block copolymers
264 c 2015-07-01
264 1b Wiley,c 2015
338 a print2 rdacarrier
500 a Updated from manuscript to article.QC 20150909
520 a A new generation of honeycomb membranes is herein described from a novel library of multipurpose linear-dendritic block copolymers. These are accomplished by combining atom transfer radical polymerization together with dendrimer chemistry and click reactions. The resulted amorphous block copolymers, with T-g between 30 and 40 degrees C, display three important functions, i.e., pore generating aromatic groups, crosslinking azides, and multiple dendritic functional groups. All block copolymers enable the successful fabrication of honeycomb membranes through the facile breath figure method. The peripheral dendritic functionality is found to influence the porous morphologies from closed pored structure with pore size of 1.12 mu m(2) to open pore structure with pore size 10.26 mu m(2). Facile UV crosslinking of the azides yields membranes with highly durable structural integrity. Upon crosslinking, the pH and thermal stability are extended beyond the noncrosslinked membranes in which the porous integrity is maintained up to 400 degrees C and pH 1-14. Taking into account the straightforward and cost-efficient strategy to generate ordered, functional, and structurally stable honeycomb membranes on various solid substrates, it is apparent that these multipurpose block copolymers may unlock future applications including use as molds for soft lithography.
650 7a NATURVETENSKAPx Kemix Polymerkemi0 (SwePub)104062 hsv//swe
650 7a NATURAL SCIENCESx Chemical Sciencesx Polymer Chemistry0 (SwePub)104062 hsv//eng
700a Walter, Marie V.u KTH,Fiber- och polymerteknologi4 aut0 (Swepub:kth)u11vpm90
700a Andrén, Oliver C. J.u KTH,Ytbehandlingsteknik4 aut0 (Swepub:kth)u1fshusr
700a Cai, Yanlingu KTH,Ytbehandlingsteknik4 aut0 (Swepub:kth)u11jzl1h
700a Malkoch, Michaelu KTH,Ytbehandlingsteknik4 aut0 (Swepub:kth)u18z6ljf
710a KTHb Ytbehandlingsteknik4 org
773t Advanced Functional Materialsd : Wileyg 25:30q 25:30x 1616-301Xx 1616-3028
8564 8u https://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-166861
8564 8u https://doi.org/10.1002/adfm.201501643

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