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4-Tert-butylpyridin...
4-Tert-butylpyridine Free Organic Hole Transporting Materials for Stable and Efficient Planar Perovskite Solar Cells
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- Xu, Bo (författare)
- Univ Washington, Dept Mat Sci & Engn, Seattle, WA 98195 USA.
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- Zhu, Zonglong (författare)
- Univ Washington, Dept Mat Sci & Engn, Seattle, WA 98195 USA.
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- Zhang, Jinbao, 1987- (författare)
- Uppsala universitet,Fysikalisk kemi
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- Liu, Hongbin (författare)
- Univ Washington, Dept Chem, Seattle, WA 98195 USA.
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- Chueh, Chu-Chen (författare)
- Univ Washington, Dept Mat Sci & Engn, Seattle, WA 98195 USA.
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- Li, Xiaosong (författare)
- Univ Washington, Dept Chem, Seattle, WA 98195 USA.
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- Jen, Alex K. -Y. (författare)
- Univ Washington, Dept Mat Sci & Engn, Seattle, WA 98195 USA.;Univ Washington, Dept Chem, Seattle, WA 98195 USA.;City Univ Hong Kong, Dept Biol & Chem, Tat Chee Ave, Kowloon, Hong Kong, Peoples R China.
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Univ Washington, Dept Mat Sci & Engn, Seattle, WA 98195 USA Fysikalisk kemi (creator_code:org_t)
- 2017-07-10
- 2017
- Engelska.
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Ingår i: Advanced Energy Materials. - : Wiley. - 1614-6832 .- 1614-6840. ; 7:19
- Relaterad länk:
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https://rss.onlineli...
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
Ämnesord
Stäng
- 4-Tert-butylpyridine (tBP) is an important additive in triarylamine-based organic hole-transporting materials (HTMs) for improving the efficiency and steady-state performance of perovskite solar cells (PVSCs). However, the low boiling point of tBP (196 degrees C) significantly affects the long-term stability and device performance of PVSCs. Herein, the design and synthesis of a series of covalently linked Spiro[fluorene-9,9'-xanthene] (SFX)-based organic HTMs and pyridine derivatives to realize efficient and stable planar PVSCs are reported. One of the tailored HTMs, N2, N2, N7, N7-tetrakis(4-methoxyphenyl)-3', 6'bis( pyridin-4-ylmethoxy) spiro[fluorene-9,9'-xanthene]-2,7-diamine (XPP) with two para-position substituted pyridines that immobilized on the SFX core unit shows a high power conversion efficiency (PCE) of 17.2% in planar CH3NH3PbI3-based PVSCs under 100 mW cm(-2) AM 1.5G solar illumination, which is much higher than the efficiency of 5.5% that using the well-known 2,2', 7,7'-tetrakis-(N, N-di-p-methoxy-phenyl-amine) 9,9'-spirobifluorene (SpiroOMeTAD) as HTM (without tBP) under the same condition. Most importantly, the pyridine-functionalized HTM-based PVSCs without tBP as additive show much better long-term stability than that of the state-of-the-art HTM SpiroOMeTAD- based solar cells that containing tBP as additive. This is the first case that the tBP-free HTMs are demonstrated in PVSCs with high PCEs and good stability. It paves the way to develop highly efficient and stable tBP-free HTMs for PVSCs toward commercial applications.
Ämnesord
- NATURVETENSKAP -- Kemi -- Fysikalisk kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Physical Chemistry (hsv//eng)
- TEKNIK OCH TEKNOLOGIER -- Materialteknik (hsv//swe)
- ENGINEERING AND TECHNOLOGY -- Materials Engineering (hsv//eng)
Nyckelord
- efficiency
- hole transport materials
- planar perovskite solar cells
- pyridine
- stable
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- ref (ämneskategori)
- art (ämneskategori)
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