WFRF:(Han Yong Jian)
Search: WFRF:(Han Yong Jian) > Photoinduced intram...
- 19 of 19
- Previous record
- Next record
- To hitlist
Photoinduced intramolecular charge transfer and S-2 fluorescence in thiophene-pi-conjugated donor-acceptor systems : Experimental and TDDFT studies
- Zhao, Guang-Jiu (author)
- Chen, Rui-Kui (author)
- Sun, Meng-Tao (author)
- show more...
- Liu, Jian-Yong (author)
- Li, Guang-Yue (author)
- Gao, Yun-Ling (author)
- Han, Ke-Li (author)
- Yang, Xi-Chuan (author)
- show less...
- (creator_code:org_t)
- Wiley, 2008
- 2008
- English.
- In: Chemistry - A European Journal. - : Wiley. - 0947-6539 .- 1521-3765. ; 14:23, s. 6935-6947
- Journal article (peer-reviewed)
Abstract
Subject headings
Close
- Experimental and theoretical methods were used to study newly synthesized thiophene-pi-cojugated donor-acceptor compounds, which were found to exhibit efficient intramolecular charge-transfer emission in polar solvents with relatively large Stokes shifts and strong solvatochromism. To gain insight into the solvatochromic behavior of these compounds, the dependence of the spectra on solvent polarity was studied on the basis of Lippert-Mataga models. We found that intramolecular charge transfer in these donor-acceptor systems is significantly dependent on the electron-with-drawing substituents at the thienyl 2-position. The dependence of the absorption and emission spectra of these compounds in methanol on the concentration of trifluoroacetic acid was used to confirm intramolecular charge-tranfer emission. Moreover, the calculated absorption and emission energies, which are in accordance with the experimental values, suggested that fluorescence can be emitted from different geometric confirmations. In addition, a novel S-2 fluorescence phenomenon for some of these compounds was also be observed. The fluorescence excitation spectra were used to confirm the S-2 fluorescence. We demonstrate that S-2 fluorescence can be explained by the calculated energy gap between the S-2 and S-1 states of these molecules. Furthermore, nonlinear optical behavior of the thiophene-pi-conjugated compound with diethylcyanomethylphosphonate substituents was predicted in theory.
Publication and Content Type
- ref (subject category)
- art (subject category)
Find in a library
- Chemistry - A European Journal (Search for host publication in LIBRIS)
To the university's database
- 19 of 19
- Previous record
- Next record
- To hitlist
Find more in SwePub
- By the author/editor
- Zhao, Guang-Jiu
- Chen, Rui-Kui
- Sun, Meng-Tao
- Liu, Jian-Yong
- Li, Guang-Yue
- Gao, Yun-Ling
- show more...
- Han, Ke-Li
- Yang, Xi-Chuan
- Sun, Licheng
- show less...
- Articles in the publication
- Chemistry - A Eu ...
- By the university
- Royal Institute of Technology
Search outside SwePub
- Extend your search to:
- Google Book Search
- Google Scholar
Kungliga biblioteket hanterar dina personuppgifter i enlighet med EU:s dataskyddsförordning (2018), GDPR. Läs mer om hur det funkar här.
Så här hanterar KB dina uppgifter vid användning av denna tjänst.
- Copyright © LIBRIS - National Library Systems
- LIBRIS.kb.se
