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Microstructure and ...
Microstructure and nonbasal-plane growth of epitaxial Ti2AlN thin films
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- Manfred, Beckers (författare)
- Institute of Ion Beam Physics and Materials Research, Forschungszentrum Rossendorf, Dresden, Germany
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- Schell, N. (författare)
- Institute of Ion Beam Physics and Materials Research, Forschungszentrum Rossendorf, Dresden, Germany
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- Martins, R.M.S. (författare)
- Institute of Ion Beam Physics and Materials Research, Forschungszentrum Rossendorf, Dresden, Germany
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- Mücklich, A. (författare)
- Institute of Ion Beam Physics and Materials Research, Forschungszentrum Rossendorf, Dresden, Germany
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- Möller, W. (författare)
- Institute of Ion Beam Physics and Materials Research, Forschungszentrum Rossendorf, Dresden, Germany
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- Hultman, Lars, 1960- (författare)
- Linköpings universitet,Tekniska högskolan,Tunnfilmsfysik
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(creator_code:org_t)
- American Institute of Physics (AIP), 2006
- 2006
- Engelska.
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Ingår i: Journal of Applied Physics. - : American Institute of Physics (AIP). - 0021-8979 .- 1089-7550. ; 99:3, s. 034902-1-034902-8
- Relaterad länk:
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
Ämnesord
Stäng
- Thin films of the Mn+1AXn (MAX) phase (M: early transition metal, A:A-group element, X: C and/or N, n=1-3) Ti2AlN were epitaxially grown onto single-crystal MgO(111) and MgO(100) substrates by dc reactive magnetron cosputtering from Ti and Al targets in an Ar/N2 gas mixture at a temperature of 690°C. To promote the nucleation of the MAX phase, a fcc (Ti0.63Al0.37)N seed layer was deposited before changing to Ti2AlN growth parameters. The nucleation processes have been studied by real-time in situ specular x-ray reflectivity. Independent of substrate orientation, the seed layer shows no roughening until its final thickness of approximately 100 Å, indicating pseudomorphic layer-by-layer growth. The MAX phase shows heteroepitaxial layer-by-layer growth on MgO(111), with increased surface roughening up to approximately 200 Å, whereas on MgO(100) the growth mode changes to Volmer-Weber-type already after three monolayers. X-ray scattering in Bragg-Brentano geometry of the final, approximately 1000 Å thick, Ti2AlN film reveals lattice parameters of c=13.463 Å and a=2.976 Å on the MgO(111) substrate and c=13.740 Å and a=2.224 Å on the MgO(100) substrate. From pole figure measurements the orientational relationship between film and substrate lattice was determined to be MgO{111}〈110〉//Ti2AlN{1012} 〈1210〉, regardless of the substrate orientation. This tilted, nonbasal-plane growth leads to a threefold grain orientation of Ti 2AlN along the MgO〈110〉 directions and a polycrystalline morphology confirmed by cross-sectional transmission electron microscopy. The growth can be assumed to take place in a lateral step-flow mode, i.e., emerging low surface free-energy (0001) planes, on which arriving atoms can diffuse until finding a step where they are bound to A facets. This growth process is irrespective of orientational relationship between substrate and film. However, in the present low-temperature case the partitioning of arriving Al and Ti atoms during nucleation is suppressed, which as a result of interfacial adaptation between substrate and film induces standing a-type planes during growth. © 2006 American Institute of Physics.
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