Sökning: WFRF:(Saethre L. J.) > Nonstoichiometric I...
Fältnamn | Indikatorer | Metadata |
---|---|---|
000 | 02590naa a2200409 4500 | |
001 | oai:DiVA.org:uu-175193 | |
003 | SwePub | |
008 | 120604s2012 | |||||||||||000 ||eng| | |
024 | 7 | a https://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-1751932 URI |
024 | 7 | a https://doi.org/10.1103/PhysRevLett.108.1930052 DOI |
040 | a (SwePub)uu | |
041 | a engb eng | |
042 | 9 SwePub | |
072 | 7 | a ref2 swepub-contenttype |
072 | 7 | a art2 swepub-publicationtype |
100 | 1 | a Söderström, Johanu Uppsala universitet,Yt- och gränsskiktsvetenskap4 aut0 (Swepub:uu)josod677 |
245 | 1 0 | a Nonstoichiometric Intensities in Core Photoelectron Spectroscopy |
264 | 1 | c 2012 |
338 | a print2 rdacarrier | |
520 | a X-ray photoemission spectroscopy is used in a great variety of research fields; one observable is the sample's stoichiometry. The stoichiometry can be deduced based on the expectation that the ionization cross sections for innershell orbitals are independent of the molecular composition. Here we used chlorine-substituted ethanes in the gas phase to investigate the apparent carbon stoichiometry. We observe a nonstoichiometric ratio for a wide range of photon energies, the ratio exhibits x-ray-absorption fine structure spectroscopy (EXAFS)-like oscillations and hundreds of eV above the C1s ionization approaches a value far from 1. These effects can be accounted for by considering the scattering of the outgoing photoelectron, which we model by multiple-scattering EXAFS calculations, and by considering the effects of losses due to monopole shakeup and shakeoff and to intramolecular inelastic scattering processes. | |
650 | 7 | a NATURVETENSKAPx Fysik0 (SwePub)1032 hsv//swe |
650 | 7 | a NATURAL SCIENCESx Physical Sciences0 (SwePub)1032 hsv//eng |
700 | 1 | a Mårtensson, Nilsu Uppsala universitet,Yt- och gränsskiktsvetenskap4 aut0 (Swepub:uu)nma32143 |
700 | 1 | a Travnikova, O.4 aut |
700 | 1 | a Patanen, M.4 aut |
700 | 1 | a Miron, C.4 aut |
700 | 1 | a Saethre, L. J.4 aut |
700 | 1 | a Borve, K. J.4 aut |
700 | 1 | a Rehr, J. J.4 aut |
700 | 1 | a Kas, J. J.4 aut |
700 | 1 | a Vila, F. D.4 aut |
700 | 1 | a Thomas, T. D.4 aut |
700 | 1 | a Svensson, Svanteu Uppsala universitet,Yt- och gränsskiktsvetenskap4 aut0 (Swepub:uu)svansven |
710 | 2 | a Uppsala universitetb Yt- och gränsskiktsvetenskap4 org |
773 | 0 | t Physical Review Lettersg 108:19, s. 193005-q 108:19<193005-x 0031-9007x 1079-7114 |
856 | 4 8 | u https://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-175193 |
856 | 4 8 | u https://doi.org/10.1103/PhysRevLett.108.193005 |
Kungliga biblioteket hanterar dina personuppgifter i enlighet med EU:s dataskyddsförordning (2018), GDPR. Läs mer om hur det funkar här.
Så här hanterar KB dina uppgifter vid användning av denna tjänst.
Kopiera och spara länken för att återkomma till aktuell vy