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Multilayer formation in spin-coated thin films of low-bandgap polyfluorene:PCBM blends

Björström, Cecilia M. (author)
Karlstads universitet,Avdelningen för fysik och elektroteknik,Materialfysik
Bernasik, Andrzej (author)
Faculty of Physics and Applied Computer Science, AGH-University of Science and Technology, Kraków, Poland
Rysz, Jakub (author)
Institute of Physics, Jagiellonian University, Kraków, Poland
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Budkowski, Andrzej (author)
Institute of Physics, Jagiellonian University, Kraków, Poland
Nilsson, Svante (author)
Karlstads universitet,Avdelningen för fysik och elektroteknik
Svensson, Mattias (author)
Department of Materials and Surface Chemistry/Polymer Technology, Chalmers University of Technology, Göteborg
Andersson, Mats R. (author)
Department of Chemical and Biological Engineering, Chalmers University of Technology
Magnusson, Kjell, 1958- (author)
Karlstads universitet,Avdelningen för fysik och elektroteknik,Materialvetenskap,Fysik
Moons, Ellen, 1966- (author)
Karlstads universitet,Avdelningen för fysik och elektroteknik,Materialvetenskap,Materialfysik
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 (creator_code:org_t)
Philadelphia : Institute of Physics Publishing (IOPP), 2005
2005
English.
In: Journal of Physics. - Philadelphia : Institute of Physics Publishing (IOPP). - 0953-8984 .- 1361-648X. ; 17:50, s. L529-L534
  • Journal article (peer-reviewed)
Abstract Subject headings
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  • Blends of the low-bandgap polymer poly[(9,9-dioctylfluorenyl-2,7-diyl)-co-5,5- (4',7'-di-2-thienyl-2',1',3'-benzothiadiazole] (APFO-3) and the fullerene derivative [6,6]-phenyl–C61–butyric acid methyl ester (PCBM) were spin-coated from chloroform solution into thin films, which were examined with dynamic secondary ion mass spectrometry. For blends with high PCBM content, the depth profiles show composition waves that were caused by surface-directed phase separation during spin-coating. The formation of such multilayer structures by spontaneous self-stratification is likely to have implications for optimization strategies for the performance of organic solar cells

Subject headings

NATURVETENSKAP  -- Fysik (hsv//swe)
NATURAL SCIENCES  -- Physical Sciences (hsv//eng)

Keyword

Soft matter
liquids and polymers
Condensed matter: electrical
magnetic and optical
Surfaces
interfaces and thin films
Nanoscale science and low-D systems
Physics
Fysik

Publication and Content Type

ref (subject category)
art (subject category)

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