Palladium-Catalyzed Allylic Sulfinylation and the Mislow-Braverman-Evans Rearrangement.

• A product quick-step: The Mislow-Braverman-Evans (MBE) rearrangement and the synthesis of sulfoxides through allylic sulfinylation have been studied. A viable DFT method for treatment of the sulfoxide-sulfenate equilibrium is presented and the ability of Pd to enhance the rate of the MBE rearrangement is shown. Of the four possible nucleophilic attacks, the two leading to the observed product are strongly preferred.

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NATURVETENSKAP  -- Kemi (hsv//swe)

NATURAL SCIENCES  -- Chemical Sciences (hsv//eng)

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