WFRF:(Gupta Arvind Kumar)
Search: WFRF:(Gupta Arvind Kumar) > One, Two Three :
- 29 of 32
- Previous record
- Next record
- To hitlist
One, Two Three : Phosphaalkene Decoration Tailoring Solubility and Electronic Properties of Truxene-Based Electron Acceptors
-
- Shameem, Muhammad Anwar (author)
- Uppsala universitet,Syntetisk molekylär kemi
-
- Wells, Jordann A. L. (author)
- Uppsala universitet,Syntetisk molekylär kemi
-
- Gupta, Arvind Kumar (author)
- Uppsala universitet,Syntetisk molekylär kemi
- show more...
- show less...
- (creator_code:org_t)
- 2023-03-27
- 2023
- English.
- In: Chemistry - A European Journal. - : John Wiley & Sons. - 0947-6539 .- 1521-3765. ; 29:32
- Journal article (peer-reviewed)
Abstract
Subject headings
Close
- We report the functionalization and deplanarization of truxenes using pnictaalkene fragments. Selective introduction of one, two, or three Mes*-Pn fragments provides up to three fully reversible reductions based on the Pn=C fragments. The incorporation of the unsaturated heteroelement fragment as well as the contortion of the truxene core result in significantly red-shifted absorption spectra and interesting opto-electronic properties which are studied by electrochemistry and spectro-electrochemistry. Incorporation of arsaalkene (As=C) motifs gives significantly milder reduction potentials and red-shifted absorption, while phosphaalkene decorated truxene P3 can be functionalized using Au(I)Cl coordination. Furthermore, solubility is markedly increased upon incorporation of the Pn-Mes* fragments which renders these materials suitable for solution processing.
Subject headings
- NATURVETENSKAP -- Kemi -- Materialkemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences -- Materials Chemistry (hsv//eng)
Keyword
- arsaalkene
- contorted aromatics
- organic radical
- phosphaalkene pi-conjugation
Publication and Content Type
- ref (subject category)
- art (subject category)
Find in a library
- Chemistry - A European Journal (Search for host publication in LIBRIS)
To the university's database
- 29 of 32
- Previous record
- Next record
- To hitlist
Find more in SwePub
- By the author/editor
- Shameem, Muhamma ...
- Wells, Jordann A ...
- Gupta, Arvind Ku ...
- Orthaber, Andrea ...
- About the subject
-
- NATURAL SCIENCES
- NATURAL SCIENCES
- and Chemical Science ...
- and Materials Chemis ...
- Articles in the publication
- Chemistry - A Eu ...
- By the university
- Uppsala University
Search outside SwePub
- Extend your search to:
- Google Book Search
- Google Scholar
Kungliga biblioteket hanterar dina personuppgifter i enlighet med EU:s dataskyddsförordning (2018), GDPR. Läs mer om hur det funkar här.
Så här hanterar KB dina uppgifter vid användning av denna tjänst.
- Copyright © LIBRIS - National Library Systems
- LIBRIS.kb.se
