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LIBRIS Formathandbok  (Information om MARC21)
FältnamnIndikatorerMetadata
00005434naa a2200613 4500
001oai:research.chalmers.se:edec9ca0-e1d7-4265-8fa5-cacbaf87c2f0
003SwePub
008231023s2024 | |||||||||||000 ||eng|
009oai:DiVA.org:liu-198676
024a https://doi.org/10.1021/acsaelm.3c009362 DOI
024a https://research.chalmers.se/publication/5379952 URI
024a https://urn.kb.se/resolve?urn=urn:nbn:se:liu:diva-1986762 URI
040 a (SwePub)cthd (SwePub)liu
041 a engb eng
042 9 SwePub
072 7a for2 swepub-publicationtype
072 7a ref2 swepub-contenttype
100a Craighero, Mariavittoria,d 1995u Chalmers tekniska högskola,Chalmers University of Technology,Chalmers Univ Technol, Sweden4 aut0 (Swepub:cth)marcra
2451 0a Impact of Oligoether Side-Chain Length on the Thermoelectric Properties of a Polar Polythiophene
264 1b AMER CHEMICAL SOC,c 2024
338 a electronic2 rdacarrier
500 a Funding Agencies|European Union [955837]; Knut and Alice Wallenberg Foundation through a Wallenberg Academy Fellowship Prolongation grant; Spanish Ministerio de Ciencia e Innovacion [CEX2019-000917-S, PID2020-119777GBI00, PDC2021-121814-I00]; China Scholarship Council [CSC201806950006]; Universitat Autonoma de Barcelona
520 a Conjugated polymers with oligoether side chains make up a promising class of thermoelectric materials. In this work, the impact of the side-chain length on the thermoelectric and mechanical properties of polythiophenes is investigated. Polymers with tri-, tetra-, or hexaethylene glycol side chains are compared, and the shortest length is found to result in thin films with the highest degree of order upon doping with the p-dopant 2,3,5,6-tetrafluoro-7,7,8,8-tetracyanoquinodimethane (F(4)TCNQ). As a result, a stiff material with an electrical conductivity of up to 830 +/- 15 S cm(-1) is obtained, resulting in a thermoelectric power factor of about 21 mu W m(-1) K-2 in the case of as-cast films. Aging at ambient conditions results in an initial decrease in thermoelectric properties but then yields a highly stable performance for at least 3 months, with values of about 200 S cm(-1) and 5 mu W m(-1) K-2. Evidently, identification of the optimal side-chain length is an important criterion for the design of conjugated polymers for organic thermoelectrics.
650 7a NATURVETENSKAPx Kemix Polymerkemi0 (SwePub)104062 hsv//swe
650 7a NATURAL SCIENCESx Chemical Sciencesx Polymer Chemistry0 (SwePub)104062 hsv//eng
650 7a NATURVETENSKAPx Kemix Oorganisk kemi0 (SwePub)104042 hsv//swe
650 7a NATURAL SCIENCESx Chemical Sciencesx Inorganic Chemistry0 (SwePub)104042 hsv//eng
650 7a TEKNIK OCH TEKNOLOGIERx Materialteknikx Annan materialteknik0 (SwePub)205992 hsv//swe
650 7a ENGINEERING AND TECHNOLOGYx Materials Engineeringx Other Materials Engineering0 (SwePub)205992 hsv//eng
653 a conjugated polymer
653 a chemical doping
653 a organicthermoelectrics
653 a side-chain length
653 a electrical conductivity
700a Guo, Jialiu Agencia Estatal Consejo Superior de Investigaciones Científicas,Spanish National Research Council,CSIC, Spain4 aut
700a Zokaei, Sepideh,d 1991u Chalmers tekniska högskola,Chalmers University of Technology,Chalmers Univ Technol, Sweden4 aut0 (Swepub:cth)zokaei
700a Griggs, Sophieu University Of Oxford,Univ Oxford, England4 aut
700a Tian, Junfuu University Of Oxford,Univ Oxford, England4 aut
700a Asatryan, Jesikau Universidade da Coruña,University of A Coruña,Univ A Coruna, Spain4 aut
700a Kimpel, Joost,d 1996u Chalmers tekniska högskola,Chalmers University of Technology,Chalmers Univ Technol, Sweden4 aut0 (Swepub:cth)kimpel
700a Kroon, Reneeu Linköpings universitet,Laboratoriet för organisk elektronik,Tekniska fakulteten,Linköping University4 aut0 (Swepub:liu)renkr29
700a Xu, Kaiu Agencia Estatal Consejo Superior de Investigaciones Científicas,Spanish National Research Council,CSIC, Spain4 aut
700a Reparaz, Juan Sebastianu Agencia Estatal Consejo Superior de Investigaciones Científicas,Spanish National Research Council,CSIC, Spain4 aut
700a Martin, Jaimeu Universidade da Coruña,University of A Coruña,Univ A Coruna, Spain; POLYMAT, Spain4 aut
700a Mcculloch, Iainu University Of Oxford,Univ Oxford, England4 aut
700a Campoy-Quiles, Marianou Agencia Estatal Consejo Superior de Investigaciones Científicas,Spanish National Research Council,CSIC, Spain4 aut
700a Müller, Christian,d 1980u Chalmers tekniska högskola,Chalmers University of Technology,Chalmers Univ Technol, Sweden4 aut0 (Swepub:cth)cmuller
710a Chalmers tekniska högskolab Chalmers Univ Technol, Sweden4 org
773t ACS Applied Electronic Materialsd : AMER CHEMICAL SOCg 6:5, s. 2909-2916q 6:5<2909-2916x 2637-6113
856u https://research.chalmers.se/publication/537995/file/537995_Fulltext.pdfx primaryx freey FULLTEXT
856u https://liu.diva-portal.org/smash/get/diva2:1806666/FULLTEXT01.pdfx primaryx Raw objecty fulltext:print
8564 8u https://doi.org/10.1021/acsaelm.3c00936
8564 8u https://research.chalmers.se/publication/537995
8564 8u https://urn.kb.se/resolve?urn=urn:nbn:se:liu:diva-198676

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