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LIBRIS Formathandbok  (Information om MARC21)
FältnamnIndikatorerMetadata
00004071naa a2200505 4500
001oai:research.chalmers.se:e565c770-a4c3-417b-9e88-615f122fdcc9
003SwePub
008230706s2023 | |||||||||||000 ||eng|
024a https://research.chalmers.se/publication/5364382 URI
024a https://doi.org/10.1016/j.ensm.2023.1028642 DOI
040 a (SwePub)cth
041 a engb eng
042 9 SwePub
072 7a art2 swepub-publicationtype
072 7a ref2 swepub-contenttype
100a Jiao, Xingxingu Xi'an Jiaotong University4 aut
2451 0a Insight of electro-chemo-mechanical process inside integrated configuration of composite cathode for solid-state batteries
264 1c 2023
520 a The complicated electro-chemo-mechanical process that occurs inside the composite cathode for solid-state batteries (SSBs), is of first importance to be insighted for the development of SSBs to seek higher energy density. Herein, exampled with layered transition-metal oxide of LiNixCoyMn1-x-yO2 (NCM), an electro-chemo-mechanical model containing electrochemical kinetics, finite-strain constitutive model and cohesive zone model was built to uncover the impact of ionic conductivity and Young's modulus (E) of solid-state electrolyte (SE) on the electro-chemo-mechanical process inside composite cathode and the intergranular failure of single cathode particle. The intergranular failure of NCM particles is powerfully determined by the Young's modulus of SE and the primary particle size, which is postponed by the coarse-primary NCM with soft SE of E=∼2 GPa. Compared with Young's modulus, increasing the ionic conductivity can uniform the distribution of both Li-ion and stress in the whole composite NCM cathode, realizing improved electrochemical performance with larger normalized capacity and lower the interfacial impendence. Hence, high-adequate ionic conductivity of 5 × 10−4 S cm−1 and soft mechanical property of E=∼2 GPa can be proposed as the guideline of SE for great electrochemical performance with prolongated lifespan of composite NCM cathode, paving an avenue to foster the application of SSBs.
650 7a NATURVETENSKAPx Kemix Oorganisk kemi0 (SwePub)104042 hsv//swe
650 7a NATURAL SCIENCESx Chemical Sciencesx Inorganic Chemistry0 (SwePub)104042 hsv//eng
650 7a TEKNIK OCH TEKNOLOGIERx Maskinteknikx Teknisk mekanik0 (SwePub)203012 hsv//swe
650 7a ENGINEERING AND TECHNOLOGYx Mechanical Engineeringx Applied Mechanics0 (SwePub)203012 hsv//eng
650 7a NATURVETENSKAPx Kemix Materialkemi0 (SwePub)104032 hsv//swe
650 7a NATURAL SCIENCESx Chemical Sciencesx Materials Chemistry0 (SwePub)104032 hsv//eng
650 7a TEKNIK OCH TEKNOLOGIERx Materialteknikx Kompositmaterial och -teknik0 (SwePub)205022 hsv//swe
650 7a ENGINEERING AND TECHNOLOGYx Materials Engineeringx Composite Science and Engineering0 (SwePub)205022 hsv//eng
650 7a NATURVETENSKAPx Fysikx Den kondenserade materiens fysik0 (SwePub)103042 hsv//swe
650 7a NATURAL SCIENCESx Physical Sciencesx Condensed Matter Physics0 (SwePub)103042 hsv//eng
653 a Electro-chemo-mechanical model
653 a Composite cathode
653 a Intergranular failure
653 a Solid-state electrolyte
653 a Solid-state batteries
700a Wang, Yongjingu Xi'an Jiaotong University4 aut
700a Chen, Yaqiu Xi'an Jiaotong University4 aut
700a Wang, Jialinu Xi'an Jiaotong University4 aut
700a Xiong, Shizhao,d 1985u Chalmers tekniska högskola,Chalmers University of Technology4 aut0 (Swepub:cth)xiongs
700a Song, Zhongxiaou Xi'an Jiaotong University4 aut
700a Xu, Xieyuu Xi'an Jiaotong University4 aut
700a Liu, Yangyangu Xi'an Jiaotong University4 aut
710a Xi'an Jiaotong Universityb Chalmers tekniska högskola4 org
773t Energy Storage Materialsg 61q 61x 2405-8297
8564 8u https://research.chalmers.se/publication/536438
8564 8u https://doi.org/10.1016/j.ensm.2023.102864

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