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Transient kinetic analysis of the oxidative dehydrogenation of propane

Creaser, Derek (author)
Luleå tekniska universitet
Andersson, B. (author)
Chalmers University of Technology, Department of Chemical Reaction Engineering
Hudgins, R.R. (author)
Department of Chemical Engineering, University of Waterloo
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Silveston, P.L. (author)
Department of Chemical Engineering, University of Waterloo
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 (creator_code:org_t)
Elsevier BV, 1999
1999
English.
In: Journal of Catalysis. - : Elsevier BV. - 0021-9517 .- 1090-2694. ; 182:1, s. 264-269
  • Journal article (peer-reviewed)
Abstract Subject headings
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  • Oxidative dehydrogenation of propane was studied using various transient techniques. Results support a redox mechanism in which propane reduces the catalyst, which is reoxidized by gas-phase oxygen. Only lattice oxygen participates in propene formation. Desorbable oxygen is a major source of poor selectivity, although lattice oxygen also causes total oxidation. Consequently, propene selectivity in the absence of gas-phase O2is superior to co-feed, steady-state selectivity at the same propane conversion. Propene selectivity is further improved by increasing the degree of catalyst reduction.

Subject headings

TEKNIK OCH TEKNOLOGIER  -- Kemiteknik -- Kemiska processer (hsv//swe)
ENGINEERING AND TECHNOLOGY  -- Chemical Engineering -- Chemical Process Engineering (hsv//eng)

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Chemical Technology
Kemisk teknologi

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Creaser, Derek
Andersson, B.
Hudgins, R.R.
Silveston, P.L.
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ENGINEERING AND TECHNOLOGY
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Luleå University of Technology

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