Search: WFRF:(Agostini Marco 1987) > A flexible and free...
Fältnamn | Indikatorer | Metadata |
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000 | 03951naa a2200469 4500 | |
001 | oai:research.chalmers.se:17ccdd4b-4b8a-40d2-9194-67830c554694 | |
003 | SwePub | |
008 | 191220s2020 | |||||||||||000 ||eng| | |
024 | 7 | a https://research.chalmers.se/publication/5144762 URI |
024 | 7 | a https://doi.org/10.1016/j.cej.2019.1234532 DOI |
040 | a (SwePub)cth | |
041 | a engb eng | |
042 | 9 SwePub | |
072 | 7 | a art2 swepub-publicationtype |
072 | 7 | a ref2 swepub-contenttype |
100 | 1 | a Haridas, Anupriya K.u Gyeongsang National University4 aut |
245 | 1 0 | a A flexible and free-standing FeS/sulfurized polyacrylonitrile hybrid anode material for high-rate sodium-ion storage |
264 | 1 | b Elsevier BV,c 2020 |
520 | a Sodium-ion based energy storage systems have attracted extensive attention due to the similarities in the mechanism of operation with lithium-ion batteries along with the additional benefit of low cost and high abundance of sodium resources. Iron sulfide-based electrodes that operate via conversion mechanism have shown ample potential for high energy sodium-ion storage. However, the problems related with tremendous volume changes and the dissolution of sodium polysulfides in the electrolyte deteriorate the cycle life and limit their application in sodium-ion batteries (SIBs). Herein, a hybrid anode material, FeS/SPAN-HNF, with iron sulfide (FeS) nanoparticles decorated in a sulfurized polyacrylonitrile (SPAN) fiber matrix is demonstrated as flexible and free-standing anode material for high-rate SIBs. Unlike previous strategies in which FeS is encapsulated in an electrochemically inactive carbon matrix, this study utilizes SPAN, an electrochemically active material, as a dual functional matrix that can efficiently buffer volume expansion and sulfur dissolution of FeS nanoparticles as well as provide significant capacity improvement. The as-designed electrode is self-standing and flexible, without current collectors, binders or additional conductive agents, thus rendering enhanced practical capacity and energy density. This electrode showed a high reversible capacity of 782.8 mAh g−1 at 200 mA g−1 with excellent high rate capability, maintaining 327.5 mAh g−1 after 500 cycles at 5 A g−1, emphasizing promising prospects for the development of flexible and high energy density SIBs. | |
650 | 7 | a TEKNIK OCH TEKNOLOGIERx Kemiteknik0 (SwePub)2042 hsv//swe |
650 | 7 | a ENGINEERING AND TECHNOLOGYx Chemical Engineering0 (SwePub)2042 hsv//eng |
650 | 7 | a NATURVETENSKAPx Kemix Materialkemi0 (SwePub)104032 hsv//swe |
650 | 7 | a NATURAL SCIENCESx Chemical Sciencesx Materials Chemistry0 (SwePub)104032 hsv//eng |
650 | 7 | a NATURVETENSKAPx Fysikx Annan fysik0 (SwePub)103992 hsv//swe |
650 | 7 | a NATURAL SCIENCESx Physical Sciencesx Other Physics Topics0 (SwePub)103992 hsv//eng |
653 | a Self-supporting electrode | |
653 | a Hybrid anode material | |
653 | a Sulfurized polyacrylonitrile | |
653 | a Iron monosulfide | |
653 | a High energy density | |
700 | 1 | a Heo, J. W.u Gyeongsang National University4 aut |
700 | 1 | a Li, Xueyingu Gyeongsang National University4 aut |
700 | 1 | a Ahn, H. J.u Gyeongsang National University4 aut |
700 | 1 | a Zhao, Xiaohuiu Soochow University4 aut |
700 | 1 | a Deng, Zhaou Soochow University4 aut |
700 | 1 | a Agostini, Marco,d 1987u Chalmers tekniska högskola,Chalmers University of Technology4 aut0 (Swepub:cth)agostini |
700 | 1 | a Matic, Aleksandar,d 1968u Chalmers tekniska högskola,Chalmers University of Technology4 aut0 (Swepub:cth)matic |
700 | 1 | a Ahn, J.u Gyeongsang National University4 aut |
710 | 2 | a Gyeongsang National Universityb Soochow University4 org |
773 | 0 | t Chemical Engineering Journald : Elsevier BVg 385:1 Aprilq 385:1 Aprilx 1385-8947 |
856 | 4 8 | u https://research.chalmers.se/publication/514476 |
856 | 4 8 | u https://doi.org/10.1016/j.cej.2019.123453 |
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