Sökning: L773:2405 8297 > A Bi-based artifici...
Fältnamn | Indikatorer | Metadata |
---|---|---|
000 | 03027naa a2200445 4500 | |
001 | oai:gup.ub.gu.se/335230 | |
003 | SwePub | |
008 | 240910s2024 | |||||||||||000 ||eng| | |
024 | 7 | a https://gup.ub.gu.se/publication/3352302 URI |
024 | 7 | a https://doi.org/10.1016/j.ensm.2023.1030872 DOI |
040 | a (SwePub)gu | |
041 | a eng | |
042 | 9 SwePub | |
072 | 7 | a ref2 swepub-contenttype |
072 | 7 | a art2 swepub-publicationtype |
100 | 1 | a Kumar, Sonal4 aut |
245 | 1 0 | a A Bi-based artificial interphase to achieve ultra-long cycling life of Al-metal anode in non-aqueous electrolyte |
264 | 1 | c 2024 |
520 | a Rechargeable aluminum-ion batteries (RAB) with Al-metal anode are regarded as cost-effective and environmentally sustainable energy storage systems. However, tapping the high volumetric capacity of the Al-anode has been a challenge because of the spontaneous and irreversible formation of the oxide layer on its surface that renders it electrochemically inactive. Though recently reported AlCl3-based electrolytes overcome this problem by breaking down this oxide layer, their highly corrosive nature hampers commercialization. Here, we investigate a novel approach to protect the Al-anode from severe oxidation by engineering an artificial protective interphase. A unique and less corrosive combination of Al(CF3SO3)3 salt and BiCl3 additive reacts with the Al-anode intrinsically to form an inorganic-rich protective bilayer. This layer is electronically insulating and significantly reduces the charge transfer resistance and surface activation energy at the anode, enabling plating/stripping at extremely low overpotential of <0.1 V that can be sustained for record-long cycling times of >4000 h. | |
650 | 7 | a NATURVETENSKAPx Kemix Materialkemi0 (SwePub)104032 hsv//swe |
650 | 7 | a NATURAL SCIENCESx Chemical Sciencesx Materials Chemistry0 (SwePub)104032 hsv//eng |
653 | a Al-ion batteries | |
653 | a Anodic overpotential | |
653 | a Multivalent batteries | |
653 | a Solid electrolyte interface | |
700 | 1 | a Rama, Prasadu Gothenburg University,Göteborgs universitet,Institutionen för kemi och molekylärbiologi,Department of Chemistry and Molecular Biology4 aut0 (Swepub:gu)xrampr |
700 | 1 | a Lieu, Wei Ying4 aut |
700 | 1 | a Zhang, Chang4 aut |
700 | 1 | a Busayaporn, Wutthikrai4 aut |
700 | 1 | a Chinnadurai, Deviprasath4 aut |
700 | 1 | a Yang, Gaoliang4 aut |
700 | 1 | a Xing, Zhenxiang4 aut |
700 | 1 | a Li, Yuanjian4 aut |
700 | 1 | a Abbas, Zareen,d 1962u Gothenburg University,Göteborgs universitet,Institutionen för kemi och molekylärbiologi,Department of Chemistry and Molecular Biology4 aut0 (Swepub:gu)xabbza |
700 | 1 | a Liu, Wei4 aut |
700 | 1 | a Seh, Zhi Wei4 aut |
710 | 2 | a Göteborgs universitetb Institutionen för kemi och molekylärbiologi4 org |
773 | 0 | t Energy Storage Materialsg 65q 65x 2405-8297 |
856 | 4 8 | u https://gup.ub.gu.se/publication/335230 |
856 | 4 8 | u https://doi.org/10.1016/j.ensm.2023.103087 |
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