Sökning: WFRF:(Pell Andrew J.) > Crystal and electro...
Fältnamn | Indikatorer | Metadata |
---|---|---|
000 | 03642naa a2200505 4500 | |
001 | oai:DiVA.org:su-197145 | |
003 | SwePub | |
008 | 210927s2021 | |||||||||||000 ||eng| | |
024 | 7 | a https://urn.kb.se/resolve?urn=urn:nbn:se:su:diva-1971452 URI |
024 | 7 | a https://doi.org/10.1038/s41467-021-24589-52 DOI |
040 | a (SwePub)su | |
041 | a engb eng | |
042 | 9 SwePub | |
072 | 7 | a ref2 swepub-contenttype |
072 | 7 | a art2 swepub-publicationtype |
100 | 1 | a Papawassiliou, Wassiliosu Stockholms universitet,Institutionen för material- och miljökemi (MMK)4 aut0 (Swepub:su)wpapa |
245 | 1 0 | a Crystal and electronic facet analysis of ultrafine Ni2P particles by solid-state NMR nanocrystallography |
264 | c 2021-07-15 | |
264 | 1 | b Springer Science and Business Media LLC,c 2021 |
338 | a print2 rdacarrier | |
520 | a Structural and morphological control of crystalline nanoparticles is crucial in the field of heterogeneous catalysis and the development of reaction specific catalysts. To achieve this, colloidal chemistry methods are combined with ab initio calculations in order to define the reaction parameters, which drive chemical reactions to the desired crystal nucleation and growth path. Key in this procedure is the experimental verification of the predicted crystal facets and their corresponding electronic structure, which in case of nanostructured materials becomes extremely difficult. Here, by employing P-31 solid-state nuclear magnetic resonance aided by advanced density functional theory calculations to obtain and assign the Knight shifts, we succeed in determining the crystal and electronic structure of the terminating surfaces of ultrafine Ni2P nanoparticles at atomic scale resolution. Our work highlights the potential of ssNMR nanocrystallography as a unique tool in the emerging field of facet-engineered nanocatalysts. Structural and morphological control of crystalline nanoparticles is crucial in heterogeneous catalysis. Applying DFT-assisted solid-state NMR spectroscopy, we determine the surface crystal and electronic structure of Ni2P nanoparticles, unveiling NMR nanocrystallography as an emerging tool in facet-engineered nanocatalysts. | |
650 | 7 | a NATURVETENSKAPx Kemi0 (SwePub)1042 hsv//swe |
650 | 7 | a NATURAL SCIENCESx Chemical Sciences0 (SwePub)1042 hsv//eng |
700 | 1 | a Carvalho, José P.u Stockholms universitet,Institutionen för material- och miljökemi (MMK)4 aut0 (Swepub:su)joal7751 |
700 | 1 | a Panopoulos, Nikolaos4 aut |
700 | 1 | a Al Wahedi, Yasser4 aut |
700 | 1 | a Shankarayya Wadi, Vijay Kumar4 aut |
700 | 1 | a Lu, Xinnan4 aut |
700 | 1 | a Polychronopoulou, Kyriaki4 aut |
700 | 1 | a Lee, Jin Bae4 aut |
700 | 1 | a Lee, Sanggil4 aut |
700 | 1 | a Kim, Chang Yeon4 aut |
700 | 1 | a Kim, Hae Jin4 aut |
700 | 1 | a Katsiotis, Marios4 aut |
700 | 1 | a Tzitzios, Vasileios4 aut |
700 | 1 | a Karagianni, Marina4 aut |
700 | 1 | a Fardis, Michael4 aut |
700 | 1 | a Papavassiliou, Georgios4 aut |
700 | 1 | a Pell, Andrew J.u Stockholms universitet,Institutionen för material- och miljökemi (MMK),Université de Lyon, France4 aut0 (Swepub:su)apell |
710 | 2 | a Stockholms universitetb Institutionen för material- och miljökemi (MMK)4 org |
773 | 0 | t Nature Communicationsd : Springer Science and Business Media LLCg 12:1q 12:1x 2041-1723 |
856 | 4 | u https://doi.org/10.1038/s41467-021-24589-5y Fulltext |
856 | 4 | u https://www.nature.com/articles/s41467-021-24589-5.pdf |
856 | 4 8 | u https://urn.kb.se/resolve?urn=urn:nbn:se:su:diva-197145 |
856 | 4 8 | u https://doi.org/10.1038/s41467-021-24589-5 |
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