C1s and O1s gas phase shake-up spectra from Mo(CO)6

Bustad, JohnnyHögskolan i Gävle,Ämnesavdelningen för naturvetenskap (författare)

Experimental high-resolution core photoelectron C1s and O1s shake-up spectra of molybdenum hexacarbonyl, Mo(CO)(6), are reported and compared with results of semiempirical INDO/CI calculations. Several hitherto unobserved peaks are identified and assigned. It is found that an intra- and inter-group classification can be used to describe the transitions. The transitions of lowest energy have Mo-CO inter-group character. Dynamical effects on the line widths of the experimental shake-up peaks are discussed. A discussion of the relevance of experimental results obtained for the Mo(CO)(6)e for CO adsorption on metal surfaces is presented.

Av författaren/redakt...: Bustad, Johnny; Enkvist, C; Lunell, S; Tillborg, H; Nilsson, A; Osborne, S; visa fler...; Sandell, A; Martensson, N; Svensson, S; visa färre...

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