Sökning: WFRF:(Shtepliuk Ivan) > Electrochemical Dep...
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000 | 02903naa a2200361 4500 | |
001 | oai:DiVA.org:liu-165496 | |
003 | SwePub | |
008 | 200505s2020 | |||||||||||000 ||eng| | |
024 | 7 | a https://urn.kb.se/resolve?urn=urn:nbn:se:liu:diva-1654962 URI |
024 | 7 | a https://doi.org/10.3390/app100414052 DOI |
040 | a (SwePub)liu | |
041 | a engb eng | |
042 | 9 SwePub | |
072 | 7 | a ref2 swepub-contenttype |
072 | 7 | a art2 swepub-publicationtype |
100 | 1 | a Shtepliuk, Ivanu Linköpings universitet,Halvledarmaterial,Tekniska fakulteten,NASU, Ukraine4 aut0 (Swepub:liu)ivash69 |
245 | 1 0 | a Electrochemical Deposition of Copper on Epitaxial Graphene |
264 | c 2020-02-19 | |
264 | 1 | b MDPI,c 2020 |
338 | a electronic2 rdacarrier | |
500 | a Funding Agencies|Swedish Foundation for Strategic research (SSF)Swedish Foundation for Strategic Research [GMT14-0077, RMA15-024]; Angpanneforeningens Forskningsstiftelse [16-541]; VR grant [2018-04962] | |
520 | a Understanding the mechanism of metal electrodeposition on graphene as the simplest building block of all graphitic materials is important for electrocatalysis and the creation of metal contacts in electronics. The present work investigates copper electrodeposition onto epitaxial graphene on 4H-SiC by experimental and computational techniques. The two subsequent single-electron transfer steps were coherently quantified by electrochemistry and density functional theory (DFT). The kinetic measurements revealed the instantaneous nucleation mechanism of copper (Cu) electrodeposition, controlled by the convergent diffusion of reactant to the limited number of nucleation sites. Cu can freely migrate across the electrode surface. These findings provide fundamental insights into the nature of copper reduction and nucleation mechanisms and can be used as a starting point for performing more sophisticated investigations and developing real applications. | |
650 | 7 | a NATURVETENSKAPx Kemix Materialkemi0 (SwePub)104032 hsv//swe |
650 | 7 | a NATURAL SCIENCESx Chemical Sciencesx Materials Chemistry0 (SwePub)104032 hsv//eng |
653 | a epitaxial graphene; copper; redox reaction; electrodeposition; voltammetry; chronoamperometry; DFT | |
700 | 1 | a Vagin, Mikhailu Linköpings universitet,Laboratoriet för organisk elektronik,Tekniska fakulteten4 aut0 (Swepub:liu)mikva87 |
700 | 1 | a Yakimova, Rositsau Linköpings universitet,Halvledarmaterial,Tekniska fakulteten4 aut0 (Swepub:liu)rosia15 |
710 | 2 | a Linköpings universitetb Halvledarmaterial4 org |
773 | 0 | t Applied Sciencesd : MDPIg 10:4q 10:4x 2076-3417 |
856 | 4 | u https://liu.diva-portal.org/smash/get/diva2:1428230/FULLTEXT01.pdfx primaryx Raw objecty fulltext:print |
856 | 4 | u https://doi.org/10.3390/app10041405 |
856 | 4 8 | u https://urn.kb.se/resolve?urn=urn:nbn:se:liu:diva-165496 |
856 | 4 8 | u https://doi.org/10.3390/app10041405 |
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