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New homogeneous and...
New homogeneous and alternating Mn(II)-azido 1D systems
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Abu-Youssef, Morsy A. M. (author)
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Escuer, A. (author)
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Vicente, R. (author)
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Mautner, F. A. (author)
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- Öhrström, Lars, 1963 (author)
- Chalmers tekniska högskola,Chalmers University of Technology
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Goher, M. A. S. (author)
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(creator_code:org_t)
- Elsevier BV, 2005
- 2005
- English.
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In: Polyhedron. - : Elsevier BV. - 0277-5387. ; 24:4, s. 557-562
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https://doi.org/10.1...
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Abstract
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- Reaction of sodium azide with manganese(II) and 4-amino-1,2,4-triazol or 3-chloropyridine leads to the 1D systems [Mn(N-3)(2) (4-amtr)(2)](,) (1) or {[Mn(N-3)(2)(3-Clpy)(2)]center dot 1/2(3-Clpy)}(n) (2), respectively. Compound 1 crystallises in the C2/m (monoclinic) group and consists of chains of Mn(II) cations bridged by double mu(1,3)-azido bridges in trans arrangement. Compound 2 crystallises in the I2/a (monoclinic) group and in this case the 1D system shows alternating double mu(1,1) and mu(1,3) bridges. Magnetic properties follow the expected antiferromagnetic (compound 1) and alternating ferro-antiferromagnetic (compound 2) behaviour. (c) 2005 Published by Elsevier Ltd.
Subject headings
- NATURVETENSKAP -- Kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences (hsv//eng)
Keyword
- ni
- complexes
- chains
- magnetochemistry
- structural-characterization
- crystal-structure
- manganese
- azido
- magnetic-behavior
- crystal structures
- mn
- 1D systems
Publication and Content Type
- art (subject category)
- ref (subject category)
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