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LIBRIS Formathandbok  (Information om MARC21)
FältnamnIndikatorerMetadata
00003679naa a2200409 4500
001oai:DiVA.org:uu-396704
003SwePub
008191108s2019 | |||||||||||000 ||eng|
0247 a https://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-3967042 URI
0247 a https://doi.org/10.1039/c9dt03049b2 DOI
040 a (SwePub)uu
041 a engb eng
042 9 SwePub
072 7a ref2 swepub-contenttype
072 7a art2 swepub-publicationtype
1001 a Gründlinger, Petrau Johannes Kepler Univ Linz, Inst Expt Phys, Surface Sci Div, Altenberger Str 69, A-4040 Linz, Austria4 aut
2451 0a Aggregation of Au(i)-complexes on amorphous substrates governed by aurophilicity
264 c 2019
264 1b ROYAL SOC CHEMISTRY,c 2019
338 a electronic2 rdacarrier
520 a In single crystals of 2-naphthylisonitrile-gold(i)-halide (halide = Cl, Br, I) complexes, AuMIDLINE HORIZONTAL ELLIPSISAu distances are found to be significantly shorter than twice the van der Waals radius, indicating attractive interactions between gold atoms in adjacent molecules. In the particular case of the studied 2-naphthylisonitrile-gold(i) complexes, homodimers are the common structural motifs, in which the linearly coordinated gold exhibits a crossed swords arrangement with the Au atoms of two molecules being at the intersection point. The crossed swords motif is preserved upon physical vapour deposition of both the chlorine and bromine derivatives on amorphous substrates like glass and glassy carbon. The determined activation energies of desorption for the chlorine (0.9 eV) and the bromine (1.2 eV) derivative are comparable to that of unsubstituted naphthalene. Using X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and ion scattering (RBS), we confirmed the chemical integrity of the molecules in thin films and revealed the orientation of the crossed swords dimers with respect to the substrate surface.
650 7a NATURVETENSKAPx Kemix Oorganisk kemi0 (SwePub)104042 hsv//swe
650 7a NATURAL SCIENCESx Chemical Sciencesx Inorganic Chemistry0 (SwePub)104042 hsv//eng
7001 a Györök, Michaelu Johannes Kepler Univ Linz, Inst Expt Phys, Surface Sci Div, Altenberger Str 69, A-4040 Linz, Austria4 aut
7001 a Wolfmayr, Sebastianu Phillipps Univ Marburg, Phys Dept, Mol Solids Grp, Renthof 7, D-35032 Marburg, Germany4 aut
7001 a Breuer, Tobiasu Phillipps Univ Marburg, Phys Dept, Mol Solids Grp, Renthof 7, D-35032 Marburg, Germany4 aut
7001 a Primetzhofer, Danielu Uppsala universitet,Tillämpad kärnfysik4 aut0 (Swepub:uu)danpr521
7001 a Bruckner, Barbarau Uppsala universitet,Tillämpad kärnfysik4 aut0 (Swepub:uu)barbr469
7001 a Monkowius, Uweu Johannes Kepler Univ Linz, Sch Educ, Altenberger Str 69, A-4040 Linz, Austria4 aut
7001 a Wagner, Thorstenu Johannes Kepler Univ Linz, Inst Expt Phys, Surface Sci Div, Altenberger Str 69, A-4040 Linz, Austria4 aut
7102 a Johannes Kepler Univ Linz, Inst Expt Phys, Surface Sci Div, Altenberger Str 69, A-4040 Linz, Austriab Phillipps Univ Marburg, Phys Dept, Mol Solids Grp, Renthof 7, D-35032 Marburg, Germany4 org
7730 t Dalton Transactionsd : ROYAL SOC CHEMISTRYg 48:39, s. 14712-14723q 48:39<14712-14723x 1477-9226x 1477-9234
8564 u https://doi.org/10.1039/c9dt03049by Fulltext
8564 u https://uu.diva-portal.org/smash/get/diva2:1368862/FULLTEXT01.pdfx primaryx Raw objecty fulltext:print
8564 u https://pubs.rsc.org/en/content/articlepdf/2019/dt/c9dt03049b
8564 8u https://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-396704
8564 8u https://doi.org/10.1039/c9dt03049b

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