Synthesis and characterisation of POCsp3OP supported Ni(II) hydroxo, hydroxycarbonyl and carbonate complexes

Jonasson, Klara J. (author): Lund University,Lunds universitet,Centrum för analys och syntes,Kemiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Centre for Analysis and Synthesis,Department of Chemistry,Departments at LTH,Faculty of Engineering, LTH

Mousa, Abdelrazek H. (author): Lund University,Lunds universitet,Centrum för analys och syntes,Kemiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Centre for Analysis and Synthesis,Department of Chemistry,Departments at LTH,Faculty of Engineering, LTH

Wendt, Ola F. (author): Lund University,Lunds universitet,Centrum för analys och syntes,Kemiska institutionen,Institutioner vid LTH,Lunds Tekniska Högskola,Centre for Analysis and Synthesis,Department of Chemistry,Departments at LTH,Faculty of Engineering, LTH

(creator_code:org_t)

Related links:: http://dx.doi.org/10...; show more...; https://lup.lub.lu.s...; https://doi.org/10.1...; show less...

Abstract Subject headings

A nickel(II) hydroxo complex (3) supported by a cyclohexyl based POCsp3OP pincer ligand (POCsp3OP = cis-1,3-Bis-(di-tert-butylphosphinito)cyclohexyl) is reported. Complex 3 reacts with CO to form the corresponding hydroxycarbonyl complex, (POCsp3OP)NiCOOH (4). Complex 3 is also reactive towards CO2, forming a bicarbonate species (5) that under reduced pressure loses 1/2 eq. of H2O and CO2 to give a binuclear, bridged carbonate complex (6). All compounds were characterized in the solid state by X-ray diffraction.

By the author/editor: Jonasson, Klara ...; Mousa, Abdelraze ...; Wendt, Ola F.

About the subject

NATURAL SCIENCES: NATURAL SCIENCES; and Chemical Science ...; and Inorganic Chemis ...

Kungliga biblioteket hanterar dina personuppgifter i enlighet med EU:s dataskyddsförordning (2018), GDPR. Läs mer om hur det funkar här.
Så här hanterar KB dina uppgifter vid användning av denna tjänst.