L773:0018 3830 OR L773:1437 434X
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The Carbonate Radical as One-Electron Oxidant of Carbohydrates in Alkaline media
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- Carlsson, Magnus (author)
- KTH,Kärnkemi
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- Stenman, David (author)
- KTH,Kärnkemi
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- Merényi, Gabor (author)
- KTH,Kärnkemi
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- (creator_code:org_t)
- 2005
- 2005
- English.
- In: Holzforschung. - 0018-3830 .- 1437-434X. ; 59:2, s. 143-146
- Journal article (peer-reviewed)
Abstract
Subject headings
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- The mechanism by which the carbonate radical anion reacts with D-glucose in alkaline aqueous solutions has been studied by means of gamma-radiolysis. From the product analysis it is concluded that the reaction sequence is initiated by a one-electron transfer between the carbonate radical anion and deprotonated D-glucose. In the presence of molecular oxygen, the major, if not only products of this reaction sequence are formic acid, arabinose and gluconic acid and reaction schemes are proposed to account for the observed formation of these products.
Subject headings
- NATURVETENSKAP -- Kemi (hsv//swe)
- NATURAL SCIENCES -- Chemical Sciences (hsv//eng)
Keyword
- carbonate radical
- deprotonated glucose
- one-electron transfer
- beta-scission
- 1
- 2 H-shift
- Chemistry
- Kemi
Publication and Content Type
- ref (subject category)
- art (subject category)
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- Royal Institute of Technology
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