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Influence of Pt, Fe...
Influence of Pt, Fe/Ni/Cr–containing intermetallics and deuterium on the oxidation of Zr-based materials
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- Anghel, Clara (författare)
- KTH,Materialvetenskap
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- Hultquist, Gunnar (författare)
- KTH,Yt- och korrosionsvetenskap
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Limbäck, Magnus (författare)
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(creator_code:org_t)
- Elsevier BV, 2005
- 2005
- Engelska.
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Ingår i: Journal of Nuclear Materials. - : Elsevier BV. - 0022-3115 .- 1873-4820. ; 340:2-3, s. 271-283
- Relaterad länk:
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https://urn.kb.se/re...
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https://doi.org/10.1...
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Abstract
Ämnesord
Stäng
- An in situ gas phase analysis technique and the 18O-SIMS technique are used to evaluate the transport of oxygen and hydrogen in oxidation of Zr-based materials. At 400 °C, it is found that oxygen dissociation efficiency decreases in the order: Pt > Zr2Fe > Zr2Ni > ZrCr2 Zircaloy-2. Two Zr-plates partly coated with 200 Å porous Pt, with and respectively without D in the substrate, were oxidized in two stages at 400 °C. SIMS depth profiles in the Pt area show that an enhanced oxidation takes place mainly by inward oxygen transport. A minimum in the oxide thickness was found near the Pt area on both Zr plates. Two Ar-filled Zircaloy-2 tubes with ZrSn liner were exposed at 370 °C to 22 mbar water, filled in from one side. Our experimental results suggest that a proper choice of the SPP composition and size distribution can lead to reduced hydrogen uptake during oxidation of Zr-based materials in water.
Ämnesord
- TEKNIK OCH TEKNOLOGIER -- Materialteknik (hsv//swe)
- ENGINEERING AND TECHNOLOGY -- Materials Engineering (hsv//eng)
Nyckelord
- high-temperature oxidation
- oxide-growth mechanisms
- zirconium alloys
- zircaloy-4 oxidation
- scale adherence
- hydrogen uptake
- kinetics
- oxygen
- water
- corrosion
- TECHNOLOGY
- TEKNIKVETENSKAP
Publikations- och innehållstyp
- ref (ämneskategori)
- art (ämneskategori)
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