Sökning: WFRF:(Lewin Erik Dr. 1979 ) > Elemental distribut...
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000 | 03135nam a2200337 4500 | |
001 | oai:DiVA.org:uu-489914 | |
003 | SwePub | |
008 | 221206| | |||||||||||000 ||eng| | |
024 | 7 | a https://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-4899142 URI |
040 | a (SwePub)uu | |
041 | a engb eng | |
042 | 9 SwePub | |
072 | 7 | a vet2 swepub-contenttype |
072 | 7 | a ovr2 swepub-publicationtype |
100 | 1 | a Zendejas Medina, León,d 1993-u Uppsala universitet,Oorganisk kemi4 aut0 (Swepub:uu)leoze157 |
245 | 1 0 | a Elemental distribution in carbon-supersaturated high entropy alloycoatings: A synchrotron-based study |
338 | a print2 rdacarrier | |
520 | a The properties of high entropy alloys (HEAs) are strongly affected by the addition of carbon past the solubility limit. Despite this is the local chemistry in these meta-stable materials not well-characterized. To better understand how carbon affects the elemental distribution of alloys whose constituent elements have widely varying carbon affinities, this paper studies amorphous sputter-deposited coatings of CoCrFeMnNi with concentrations of up to 11\% carbon. Hard x-ray photoelectron spectroscopy (HAXPES), near-edge x-ray absorption fine structure (NEXAFS), and transmission electron microscopy (TEM) were used to determine how each metallic element is affected by the presence of carbon. As-deposited samples are also compared to annealed samples to study the thermal stability and the Calphad method was used to predict the thermodynamic equilibrium state. All five component metals had weak interaction with carbon, including Ni which had a less metallic character in the carbon-containing samples. While elemental segregation is expected at all temperatures at thermodynamic equilibrium, carbon did not promote segregation in the as-deposited samples. During annealing, however, the elements rearranged and formed a mixture of alloy phases and crystalline Cr-rich carbides. Rearrangement of the elements also occurred in the surface oxide, where Mn became dominant. The combination of techniques to characterize HEAs revealed promising trends for future research into these important materials. | |
650 | 7 | a NATURVETENSKAPx Kemix Materialkemi0 (SwePub)104032 hsv//swe |
650 | 7 | a NATURAL SCIENCESx Chemical Sciencesx Materials Chemistry0 (SwePub)104032 hsv//eng |
653 | a hard x-ray photoelectron spectroscopy | |
653 | a synchrotron | |
653 | a x-ray absorption | |
653 | a high entropy alloy | |
700 | 1 | a Donzel-Gargand, Olivieru Uppsala universitet,Solcellsteknik4 aut0 (Swepub:uu)olido551 |
700 | 1 | a von Fieandt, Kristinau Uppsala universitet,Oorganisk kemi4 aut0 (Swepub:uu)krijo958 |
700 | 1 | a Lewin, Erik,c Dr.d 1979-u Uppsala universitet,Oorganisk kemi4 aut0 (Swepub:uu)leeri169 |
700 | 1 | a Jansson, Ulf,d 1960-u Uppsala universitet,Oorganisk kemi4 aut0 (Swepub:uu)uja03434 |
700 | 1 | a Lindblad, Rebecka,c Dr,d 1984-u Uppsala universitet,Fysikalisk kemi,Oorganisk kemi4 aut0 (Swepub:uu)rebsc244 |
710 | 2 | a Uppsala universitetb Oorganisk kemi4 org |
856 | 4 8 | u https://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-489914 |
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