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WFRF:(Lewin Erik Dr. 1979 )
 

Sökning: WFRF:(Lewin Erik Dr. 1979 ) > Elemental distribut...

LIBRIS Formathandbok  (Information om MARC21)
FältnamnIndikatorerMetadata
00003135nam a2200337 4500
001oai:DiVA.org:uu-489914
003SwePub
008221206| | |||||||||||000 ||eng|
024a https://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-4899142 URI
040 a (SwePub)uu
041 a engb eng
042 9 SwePub
072 7a vet2 swepub-contenttype
072 7a ovr2 swepub-publicationtype
100a Zendejas Medina, León,d 1993-u Uppsala universitet,Oorganisk kemi4 aut0 (Swepub:uu)leoze157
2451 0a Elemental distribution in carbon-supersaturated high entropy alloycoatings: A synchrotron-based study
338 a print2 rdacarrier
520 a The properties of high entropy alloys (HEAs) are strongly affected by the addition of carbon past the solubility limit. Despite this is the local chemistry in these meta-stable materials not well-characterized. To better understand how carbon affects the elemental distribution of alloys whose constituent elements have widely varying carbon affinities, this paper studies amorphous sputter-deposited coatings of CoCrFeMnNi with concentrations of up to 11\% carbon. Hard x-ray photoelectron spectroscopy (HAXPES), near-edge x-ray absorption fine structure (NEXAFS), and transmission electron microscopy (TEM) were used to determine how each metallic element is affected by the presence of carbon. As-deposited samples are also compared to annealed samples to study the thermal stability and the Calphad method was used to predict the thermodynamic equilibrium state. All five component metals had weak interaction with carbon, including Ni which had a less metallic character in the carbon-containing samples. While elemental segregation is expected at all temperatures at thermodynamic equilibrium, carbon did not promote segregation in the as-deposited samples. During annealing, however, the elements rearranged and formed a mixture of alloy phases and crystalline Cr-rich carbides. Rearrangement of the elements also occurred in the surface oxide, where Mn became dominant. The combination of techniques to characterize HEAs revealed promising trends for future research into these important materials.
650 7a NATURVETENSKAPx Kemix Materialkemi0 (SwePub)104032 hsv//swe
650 7a NATURAL SCIENCESx Chemical Sciencesx Materials Chemistry0 (SwePub)104032 hsv//eng
653 a hard x-ray photoelectron spectroscopy
653 a synchrotron
653 a x-ray absorption
653 a high entropy alloy
700a Donzel-Gargand, Olivieru Uppsala universitet,Solcellsteknik4 aut0 (Swepub:uu)olido551
700a von Fieandt, Kristinau Uppsala universitet,Oorganisk kemi4 aut0 (Swepub:uu)krijo958
700a Lewin, Erik,c Dr.d 1979-u Uppsala universitet,Oorganisk kemi4 aut0 (Swepub:uu)leeri169
700a Jansson, Ulf,d 1960-u Uppsala universitet,Oorganisk kemi4 aut0 (Swepub:uu)uja03434
700a Lindblad, Rebecka,c Dr,d 1984-u Uppsala universitet,Fysikalisk kemi,Oorganisk kemi4 aut0 (Swepub:uu)rebsc244
710a Uppsala universitetb Oorganisk kemi4 org
8564 8u https://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-489914

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